The effect of sunflower seed shell extract (Helianthus annus) as an organic inhibitor on carbon steel in 1 M HCl

Currently, the increasing demand for environmentally friendly corrosion inhibitors. Sustainable organic inhibitor innovations can be an alternative in the industrial world that still uses hazardous chemical inhibitors. Carbon Steel is a material that is often used in the oil and gas industry. This t...

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Main Authors: Pramudya Imawan Santosa, W.B. Wan Nik, Atria Pradityana, Farah Khosfirah, Muhammad Saiful Rizal, Eddy Widiyono, Hari Subiyanto, Nur Husodo, Ahmat Safa'at, Rizaldy Hakim Ash Shidieqqy, Muhammad Lukman Hakim
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Case Studies in Chemical and Environmental Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666016425000489
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author Pramudya Imawan Santosa
W.B. Wan Nik
Atria Pradityana
Farah Khosfirah
Muhammad Saiful Rizal
Eddy Widiyono
Hari Subiyanto
Nur Husodo
Ahmat Safa'at
Rizaldy Hakim Ash Shidieqqy
Muhammad Lukman Hakim
author_facet Pramudya Imawan Santosa
W.B. Wan Nik
Atria Pradityana
Farah Khosfirah
Muhammad Saiful Rizal
Eddy Widiyono
Hari Subiyanto
Nur Husodo
Ahmat Safa'at
Rizaldy Hakim Ash Shidieqqy
Muhammad Lukman Hakim
author_sort Pramudya Imawan Santosa
collection DOAJ
description Currently, the increasing demand for environmentally friendly corrosion inhibitors. Sustainable organic inhibitor innovations can be an alternative in the industrial world that still uses hazardous chemical inhibitors. Carbon Steel is a material that is often used in the oil and gas industry. This type of steel is resistant to significant corrosion, so an effective solution is needed to minimise material degradation. This study investigates the potential of sunflower (Helianthus annus) seed shell extract, SSSE. as a sustainable, environmentally friendly corrosion inhibitor for steel in concentrated hydrochloric acid (1 M HCl), where these conditions are representative of an industrially hazardous environment. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarisation (PDP) methods were used in this study. With these two approaches, SSSE showed a high inhibition efficiency of 99.56 % at a concentration of 400 ppm, effectively reducing both anodic and cathodic corrosion reactions. Scanning electron microscopy (SEM) showed the formed protective layer on the steel surface, significantly reducing corrosion. These findings highlight SSSE as a feasible and environmentally friendly alternative to conventional inhibitors, showing great potential applications in various acidic environments.
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publishDate 2025-06-01
publisher Elsevier
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series Case Studies in Chemical and Environmental Engineering
spelling doaj-art-04cb9de7c3de4bf9b4c558ad52fcd65b2025-02-10T04:34:55ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642025-06-0111101141The effect of sunflower seed shell extract (Helianthus annus) as an organic inhibitor on carbon steel in 1 M HClPramudya Imawan Santosa0W.B. Wan Nik1Atria Pradityana2Farah Khosfirah3Muhammad Saiful Rizal4Eddy Widiyono5Hari Subiyanto6Nur Husodo7Ahmat Safa'at8Rizaldy Hakim Ash Shidieqqy9Muhammad Lukman Hakim10Faculty of Engineering, Naval Engineering, Universitas Muhammadiyah Surabaya, Surabaya, IndonesiaFaculty of Ocean Engineering Technology and Informatics, Universiti Malaysia Terengganu, Kuala Nerus, 21030, Terengganu, MalaysiaDept. of Mechanical Industrial Engineering, Vocational Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, Indonesia; Corresponding author.Dept. of Mechanical Engineering, Industrial Technology and Systems Engineering Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, IndonesiaDept. of Mechanical Industrial Engineering, Vocational Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, IndonesiaDept. of Mechanical Industrial Engineering, Vocational Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, IndonesiaDept. of Mechanical Industrial Engineering, Vocational Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, IndonesiaDept. of Mechanical Industrial Engineering, Vocational Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, IndonesiaDept. of Mechanical Industrial Engineering, Vocational Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, IndonesiaDept. of Mechanical Industrial Engineering, Vocational Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, IndonesiaDept. of Mechanical Industrial Engineering, Vocational Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, IndonesiaCurrently, the increasing demand for environmentally friendly corrosion inhibitors. Sustainable organic inhibitor innovations can be an alternative in the industrial world that still uses hazardous chemical inhibitors. Carbon Steel is a material that is often used in the oil and gas industry. This type of steel is resistant to significant corrosion, so an effective solution is needed to minimise material degradation. This study investigates the potential of sunflower (Helianthus annus) seed shell extract, SSSE. as a sustainable, environmentally friendly corrosion inhibitor for steel in concentrated hydrochloric acid (1 M HCl), where these conditions are representative of an industrially hazardous environment. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarisation (PDP) methods were used in this study. With these two approaches, SSSE showed a high inhibition efficiency of 99.56 % at a concentration of 400 ppm, effectively reducing both anodic and cathodic corrosion reactions. Scanning electron microscopy (SEM) showed the formed protective layer on the steel surface, significantly reducing corrosion. These findings highlight SSSE as a feasible and environmentally friendly alternative to conventional inhibitors, showing great potential applications in various acidic environments.http://www.sciencedirect.com/science/article/pii/S2666016425000489CorrosionOrganic inhibitorSunflower seed shell extractCarbon steel pipeHCL 1 M
spellingShingle Pramudya Imawan Santosa
W.B. Wan Nik
Atria Pradityana
Farah Khosfirah
Muhammad Saiful Rizal
Eddy Widiyono
Hari Subiyanto
Nur Husodo
Ahmat Safa'at
Rizaldy Hakim Ash Shidieqqy
Muhammad Lukman Hakim
The effect of sunflower seed shell extract (Helianthus annus) as an organic inhibitor on carbon steel in 1 M HCl
Case Studies in Chemical and Environmental Engineering
Corrosion
Organic inhibitor
Sunflower seed shell extract
Carbon steel pipe
HCL 1 M
title The effect of sunflower seed shell extract (Helianthus annus) as an organic inhibitor on carbon steel in 1 M HCl
title_full The effect of sunflower seed shell extract (Helianthus annus) as an organic inhibitor on carbon steel in 1 M HCl
title_fullStr The effect of sunflower seed shell extract (Helianthus annus) as an organic inhibitor on carbon steel in 1 M HCl
title_full_unstemmed The effect of sunflower seed shell extract (Helianthus annus) as an organic inhibitor on carbon steel in 1 M HCl
title_short The effect of sunflower seed shell extract (Helianthus annus) as an organic inhibitor on carbon steel in 1 M HCl
title_sort effect of sunflower seed shell extract helianthus annus as an organic inhibitor on carbon steel in 1 m hcl
topic Corrosion
Organic inhibitor
Sunflower seed shell extract
Carbon steel pipe
HCL 1 M
url http://www.sciencedirect.com/science/article/pii/S2666016425000489
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