Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes
A series of solid-state structures of gold(I) complexes using the semi-rigid cis-1,2- bis(diphenylphosphino)ethene (= cis-bdppe) ligand are reported. The proximity of the phosphine donor atoms of the bidentate ligand framework greatly favors formation of mononuclear over di- nuclear complexes. Struc...
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Académie des sciences
2024-08-01
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| Series: | Comptes Rendus. Chimie |
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| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.328/ |
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| author | Fayet, Océane Yvonne Odette Crespi, Stefano Orthaber, Andreas |
| author_facet | Fayet, Océane Yvonne Odette Crespi, Stefano Orthaber, Andreas |
| author_sort | Fayet, Océane Yvonne Odette |
| collection | DOAJ |
| description | A series of solid-state structures of gold(I) complexes using the semi-rigid cis-1,2- bis(diphenylphosphino)ethene (= cis-bdppe) ligand are reported. The proximity of the phosphine donor atoms of the bidentate ligand framework greatly favors formation of mononuclear over di- nuclear complexes. Structural analysis and theoretical studies shed further light on counter intermolecular packing motifs in the solid state including interactions of solvent, ligand and counterion fragments. |
| format | Article |
| id | doaj-art-07a1e1002d8e4337a02133b83a1044dd |
| institution | Kabale University |
| issn | 1878-1543 |
| language | English |
| publishDate | 2024-08-01 |
| publisher | Académie des sciences |
| record_format | Article |
| series | Comptes Rendus. Chimie |
| spelling | doaj-art-07a1e1002d8e4337a02133b83a1044dd2025-02-07T13:39:09ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432024-08-0127S111312310.5802/crchim.32810.5802/crchim.328Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexesFayet, Océane Yvonne Odette0Crespi, Stefano1https://orcid.org/0000-0002-0279-4903Orthaber, Andreas2https://orcid.org/0000-0001-5403-9902Department of Chemistry Ångström Laboratories – Synthetic Molecular Chemistry, BOX 523 Uppsala (75120), SwedenDepartment of Chemistry Ångström Laboratories – Synthetic Molecular Chemistry, BOX 523 Uppsala (75120), SwedenDepartment of Chemistry Ångström Laboratories – Synthetic Molecular Chemistry, BOX 523 Uppsala (75120), SwedenA series of solid-state structures of gold(I) complexes using the semi-rigid cis-1,2- bis(diphenylphosphino)ethene (= cis-bdppe) ligand are reported. The proximity of the phosphine donor atoms of the bidentate ligand framework greatly favors formation of mononuclear over di- nuclear complexes. Structural analysis and theoretical studies shed further light on counter intermolecular packing motifs in the solid state including interactions of solvent, ligand and counterion fragments.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.328/Aurophilic interactionsGold(I) complexSingle crystal X-ray diffraction |
| spellingShingle | Fayet, Océane Yvonne Odette Crespi, Stefano Orthaber, Andreas Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes Comptes Rendus. Chimie Aurophilic interactions Gold(I) complex Single crystal X-ray diffraction |
| title | Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes |
| title_full | Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes |
| title_fullStr | Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes |
| title_full_unstemmed | Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes |
| title_short | Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes |
| title_sort | synthesis and characterization of cis bisdiphenylphosphinoethene gold i complexes |
| topic | Aurophilic interactions Gold(I) complex Single crystal X-ray diffraction |
| url | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.328/ |
| work_keys_str_mv | AT fayetoceaneyvonneodette synthesisandcharacterizationofcisbisdiphenylphosphinoethenegoldicomplexes AT crespistefano synthesisandcharacterizationofcisbisdiphenylphosphinoethenegoldicomplexes AT orthaberandreas synthesisandcharacterizationofcisbisdiphenylphosphinoethenegoldicomplexes |