Research on the photoelectrical properties of TiO2-doped V2O5/FTO nanocomposite thin films under thermal and electrical excitation

The TiO2-doped V2O5/FTO nanocomposite thin films were prepared on the FTO substrates by sol-gel method and post-annealing process, and the MSM structural devices based on the prepared films were fabricated by sputtering, photolithography and etching techniques. SEM, XRD, and XPS were respectively us...

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Main Authors: Xue Chang, Li Yi, Zhang Haoting, He Weiye, Peng Weiye, Dai Wenyan, Yuan Zhen, Lin Ke, Wang Wei, Shi Zhangqing, Liu Hongwei
Format: Article
Language:English
Published: EDP Sciences 2025-01-01
Series:Journal of the European Optical Society-Rapid Publications
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Online Access:https://jeos.edpsciences.org/articles/jeos/full_html/2025/01/jeos20240068/jeos20240068.html
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author Xue Chang
Li Yi
Zhang Haoting
He Weiye
Peng Weiye
Dai Wenyan
Yuan Zhen
Lin Ke
Wang Wei
Shi Zhangqing
Liu Hongwei
author_facet Xue Chang
Li Yi
Zhang Haoting
He Weiye
Peng Weiye
Dai Wenyan
Yuan Zhen
Lin Ke
Wang Wei
Shi Zhangqing
Liu Hongwei
author_sort Xue Chang
collection DOAJ
description The TiO2-doped V2O5/FTO nanocomposite thin films were prepared on the FTO substrates by sol-gel method and post-annealing process, and the MSM structural devices based on the prepared films were fabricated by sputtering, photolithography and etching techniques. SEM, XRD, and XPS were respectively used to study the morphology, structure and composition of the film, and the electrical and optical regulations of the device were measured by using spectrophotometry and semiconductor parameter analyzer. In the temperature range of 20–360 °C, the maximum modulation amplitude of the TiO2-doped V2O5/FTO film in the 400–1600 nm band was 18.282% and the modulation of the V2O5/FTO film was increased by 9.663% after TiO2-doping. The resistance of the FTO/V2O5-TiO2/FTO device reduced by 3–4 orders of magnitude by comparing with the FTO/V2O5/FTO device. The FTO/V2O5-TiO2/FTO device underwent semiconductor-metal state transition (SMT) around 259.91 °C. Under the applied voltage of 0–5 V, the maximum transmittance variations could reach 8.821%, 7.174% and 11.540% in 400–1600 nm band at the temperature of 20 °C, 40 °C and 80 °C, respectively. The outstanding optical and electrical regulation properties and the favorable cycling stability make the nanocomposite film expected to be applied in the field of optoelectronic devices.
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institution Kabale University
issn 1990-2573
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publishDate 2025-01-01
publisher EDP Sciences
record_format Article
series Journal of the European Optical Society-Rapid Publications
spelling doaj-art-0ad70e2511a84649a23819104091b7202025-02-07T08:23:02ZengEDP SciencesJournal of the European Optical Society-Rapid Publications1990-25732025-01-01211610.1051/jeos/2025001jeos20240068Research on the photoelectrical properties of TiO2-doped V2O5/FTO nanocomposite thin films under thermal and electrical excitationXue Chang0Li Yi1Zhang Haoting2He Weiye3Peng Weiye4Dai Wenyan5Yuan Zhen6Lin Ke7Wang Wei8Shi Zhangqing9Liu Hongwei10College of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyCollege of Optical-Electrical and Computer Engineering, University of Shanghai for Science and TechnologyThe TiO2-doped V2O5/FTO nanocomposite thin films were prepared on the FTO substrates by sol-gel method and post-annealing process, and the MSM structural devices based on the prepared films were fabricated by sputtering, photolithography and etching techniques. SEM, XRD, and XPS were respectively used to study the morphology, structure and composition of the film, and the electrical and optical regulations of the device were measured by using spectrophotometry and semiconductor parameter analyzer. In the temperature range of 20–360 °C, the maximum modulation amplitude of the TiO2-doped V2O5/FTO film in the 400–1600 nm band was 18.282% and the modulation of the V2O5/FTO film was increased by 9.663% after TiO2-doping. The resistance of the FTO/V2O5-TiO2/FTO device reduced by 3–4 orders of magnitude by comparing with the FTO/V2O5/FTO device. The FTO/V2O5-TiO2/FTO device underwent semiconductor-metal state transition (SMT) around 259.91 °C. Under the applied voltage of 0–5 V, the maximum transmittance variations could reach 8.821%, 7.174% and 11.540% in 400–1600 nm band at the temperature of 20 °C, 40 °C and 80 °C, respectively. The outstanding optical and electrical regulation properties and the favorable cycling stability make the nanocomposite film expected to be applied in the field of optoelectronic devices.https://jeos.edpsciences.org/articles/jeos/full_html/2025/01/jeos20240068/jeos20240068.htmlv2o5titanium dioxidenanocomposite filmoptoelectronic device
spellingShingle Xue Chang
Li Yi
Zhang Haoting
He Weiye
Peng Weiye
Dai Wenyan
Yuan Zhen
Lin Ke
Wang Wei
Shi Zhangqing
Liu Hongwei
Research on the photoelectrical properties of TiO2-doped V2O5/FTO nanocomposite thin films under thermal and electrical excitation
Journal of the European Optical Society-Rapid Publications
v2o5
titanium dioxide
nanocomposite film
optoelectronic device
title Research on the photoelectrical properties of TiO2-doped V2O5/FTO nanocomposite thin films under thermal and electrical excitation
title_full Research on the photoelectrical properties of TiO2-doped V2O5/FTO nanocomposite thin films under thermal and electrical excitation
title_fullStr Research on the photoelectrical properties of TiO2-doped V2O5/FTO nanocomposite thin films under thermal and electrical excitation
title_full_unstemmed Research on the photoelectrical properties of TiO2-doped V2O5/FTO nanocomposite thin films under thermal and electrical excitation
title_short Research on the photoelectrical properties of TiO2-doped V2O5/FTO nanocomposite thin films under thermal and electrical excitation
title_sort research on the photoelectrical properties of tio2 doped v2o5 fto nanocomposite thin films under thermal and electrical excitation
topic v2o5
titanium dioxide
nanocomposite film
optoelectronic device
url https://jeos.edpsciences.org/articles/jeos/full_html/2025/01/jeos20240068/jeos20240068.html
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