INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY
On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral en...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2020-07-01
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| Series: | Journal of Engineering Studies and Research |
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| Online Access: | https://jesr.ub.ro/index.php/1/article/view/208 |
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| author | DAME SEYE ASSANE TOURE CHEIKH ABDOUL KHADIR DIOP LIBASSE DIOP |
| author_facet | DAME SEYE ASSANE TOURE CHEIKH ABDOUL KHADIR DIOP LIBASSE DIOP |
| author_sort | DAME SEYE |
| collection | DOAJ |
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On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral environments around the metallic centres. The MX2 behaves as discrete chains. For most of the structures, when intermolecular hydrogen bonds are considered, supramolecular architectures may be obtained.
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| format | Article |
| id | doaj-art-244cc9b0a5d9479bba83aaaeee20a36d |
| institution | Kabale University |
| issn | 2068-7559 2344-4932 |
| language | English |
| publishDate | 2020-07-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj-art-244cc9b0a5d9479bba83aaaeee20a36d2025-02-09T11:37:35ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322020-07-01263INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDYDAME SEYEASSANE TOURECHEIKH ABDOUL KHADIR DIOPLIBASSE DIOP On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral environments around the metallic centres. The MX2 behaves as discrete chains. For most of the structures, when intermolecular hydrogen bonds are considered, supramolecular architectures may be obtained. https://jesr.ub.ro/index.php/1/article/view/208intermolecular hydrogen bonds, discrete structures, infinite chain, supramolecular architecture |
| spellingShingle | DAME SEYE ASSANE TOURE CHEIKH ABDOUL KHADIR DIOP LIBASSE DIOP INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY Journal of Engineering Studies and Research intermolecular hydrogen bonds, discrete structures, infinite chain, supramolecular architecture |
| title | INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_full | INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_fullStr | INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_full_unstemmed | INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_short | INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
| title_sort | interactions between cetyltrimethylammonium or tetrametylammmonium bromide and mcl2 or mcl5 m hg cu zn co ni cd and nb in mononuclear complexes synthesis and infrared study |
| topic | intermolecular hydrogen bonds, discrete structures, infinite chain, supramolecular architecture |
| url | https://jesr.ub.ro/index.php/1/article/view/208 |
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