SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowin...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2020-07-01
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| Series: | Journal of Engineering Studies and Research |
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| Online Access: | https://jesr.ub.ro/index.php/1/article/view/227 |
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| _version_ | 1823863745954185216 |
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| author | MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP |
| author_facet | MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP |
| author_sort | MODOU SARR |
| collection | DOAJ |
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Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowing (C6H5CH2)NH2)3O2C(CH2)2PO3 or [CyNH3(HO2POCH2-N(CH2 CO2H)2]2 and SnPh3Cl or SnCl2×2H2O to react in ethanolic media have been characterized by elemental analyses, infrared and Mossbauer techniques. The suggested structures, while considering the anionic counterpart, are discrete, dimeric, double and triple metallic components or of infinite chain types, the anion behaving as a monochelating, a bichelating or a bidentate ligand. In OH containing structures, when extra hydrogen bonds are considered, supramolecular architectures may be obtained.
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| format | Article |
| id | doaj-art-2a9d7d140e6543dfa8e4d4fd32b7798a |
| institution | Kabale University |
| issn | 2068-7559 2344-4932 |
| language | English |
| publishDate | 2020-07-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj-art-2a9d7d140e6543dfa8e4d4fd32b7798a2025-02-09T11:37:29ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322020-07-01263SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTSMODOU SARRAMINATA DIASSE-SARRLIBASSE DIOP Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowing (C6H5CH2)NH2)3O2C(CH2)2PO3 or [CyNH3(HO2POCH2-N(CH2 CO2H)2]2 and SnPh3Cl or SnCl2×2H2O to react in ethanolic media have been characterized by elemental analyses, infrared and Mossbauer techniques. The suggested structures, while considering the anionic counterpart, are discrete, dimeric, double and triple metallic components or of infinite chain types, the anion behaving as a monochelating, a bichelating or a bidentate ligand. In OH containing structures, when extra hydrogen bonds are considered, supramolecular architectures may be obtained. https://jesr.ub.ro/index.php/1/article/view/227bidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architectures |
| spellingShingle | MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS Journal of Engineering Studies and Research bidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architectures |
| title | SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS |
| title_full | SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS |
| title_fullStr | SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS |
| title_full_unstemmed | SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS |
| title_short | SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS |
| title_sort | synthesis and infrared study of some phenylphosphonate diphenylphosphinate and acetatophosphonate new organotin iv derivatives and adducts |
| topic | bidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architectures |
| url | https://jesr.ub.ro/index.php/1/article/view/227 |
| work_keys_str_mv | AT modousarr synthesisandinfraredstudyofsomephenylphosphonatediphenylphosphinateandacetatophosphonateneworganotinivderivativesandadducts AT aminatadiassesarr synthesisandinfraredstudyofsomephenylphosphonatediphenylphosphinateandacetatophosphonateneworganotinivderivativesandadducts AT libassediop synthesisandinfraredstudyofsomephenylphosphonatediphenylphosphinateandacetatophosphonateneworganotinivderivativesandadducts |