A comparative study of the production of methyl esters from non-edible oils as potential feedstocks: Process optimization and two-step biodiesel characterization

The growing demand for sustainable and renewable energy sources has intensified interest in biodiesel production from non-edible vegetable oils, offering an alternative to reduce reliance on edible oils. This study focuses on the biodiesel potential of Jatropha curcas, Calophyllum inophyllum, and Ce...

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Main Authors: Jassinnee Milano, Mei Yin Ong, Sieh Kiong Tiong, F. Ideris, A.S. Silitonga, A.H. Sebayang, Chung Hong Tan, I.M.R. Fattah, Zahra Fona, Nazia Hossain
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Results in Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590123025003706
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author Jassinnee Milano
Mei Yin Ong
Sieh Kiong Tiong
F. Ideris
A.S. Silitonga
A.H. Sebayang
Chung Hong Tan
I.M.R. Fattah
Zahra Fona
Nazia Hossain
author_facet Jassinnee Milano
Mei Yin Ong
Sieh Kiong Tiong
F. Ideris
A.S. Silitonga
A.H. Sebayang
Chung Hong Tan
I.M.R. Fattah
Zahra Fona
Nazia Hossain
author_sort Jassinnee Milano
collection DOAJ
description The growing demand for sustainable and renewable energy sources has intensified interest in biodiesel production from non-edible vegetable oils, offering an alternative to reduce reliance on edible oils. This study focuses on the biodiesel potential of Jatropha curcas, Calophyllum inophyllum, and Ceiba pentandra oils, which are rich in free fatty acids.This study explores the biodiesel potential of Jatropha curcas, Calophyllum inophyllum, and Ceiba pentandra oils, focusing on developing a unified set of process conditions for effectives conversion. The response surface methodology (RSM), a nonlinear regression approach, was employed to optimize the transesterification process, aiming to simulate and apply the same process parameters across all three oils. Five key factors affecting the conversion of biodiesel: molar ratio, potassium hydroxide, temperature, time, and speed agitation, using two-stage analysis of variance. The optimal experimental conditions for the transesterification process were 0.5 wt% of potassium hydroxide catalyst, a temperature at 50 °C, molar ratio of 9:1, time of reaction at 60 min, and agitation speed of 811 rpm. Under these optimal conditions, >90 % biodiesel yield was obtained. The fuel properties of the biodiesel were evaluated and found to meet ASTM D6751 standards, exhibiting characteristics comparable to conventional diesel. These findings demonstrate the feasibility of using non-edible oils under a single optimized process, paving the way for cost-effective and scalable biodiesel production suitable for compression ignition engines.
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publishDate 2025-03-01
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spelling doaj-art-449d941f359e4c0dbcb0f6f30f99cb4a2025-02-11T04:35:24ZengElsevierResults in Engineering2590-12302025-03-0125104285A comparative study of the production of methyl esters from non-edible oils as potential feedstocks: Process optimization and two-step biodiesel characterizationJassinnee Milano0Mei Yin Ong1Sieh Kiong Tiong2F. Ideris3A.S. Silitonga4A.H. Sebayang5Chung Hong Tan6I.M.R. Fattah7Zahra Fona8Nazia Hossain9Institute of Sustainable Energy, Universiti Tenaga Nasional, 43000 Kajang, Selangor Malaysia; Corresponding authors.Institute of Sustainable Energy, Universiti Tenaga Nasional, 43000 Kajang, Selangor MalaysiaInstitute of Sustainable Energy, Universiti Tenaga Nasional, 43000 Kajang, Selangor MalaysiaInstitute of Sustainable Energy, Universiti Tenaga Nasional, 43000 Kajang, Selangor MalaysiaCentre for Technology in Water and Wastewater, School of Civil and Environmental Engineering, Faculty of Engineering and Information Technology, University of Technology Sydney, NSW 2007, Australia; Center of Renewable Energy, Department of Mechanical Engineering, Politeknik Negeri Medan, 20155 Medan, Indonesia; Corresponding authors.Center of Renewable Energy, Department of Mechanical Engineering, Politeknik Negeri Medan, 20155 Medan, IndonesiaInstitute of Sustainable Energy, Universiti Tenaga Nasional, 43000 Kajang, Selangor MalaysiaCentre for Technology in Water and Wastewater, School of Civil and Environmental Engineering, Faculty of Engineering and Information Technology, University of Technology Sydney, NSW 2007, AustraliaDepartment of Chemical Engineering, Politeknik Negeri Lhokseumawe, 24301, Aceh, IndonesiaSchool of Engineering, RMIT University, Melbourne, VIC 3001, AustraliaThe growing demand for sustainable and renewable energy sources has intensified interest in biodiesel production from non-edible vegetable oils, offering an alternative to reduce reliance on edible oils. This study focuses on the biodiesel potential of Jatropha curcas, Calophyllum inophyllum, and Ceiba pentandra oils, which are rich in free fatty acids.This study explores the biodiesel potential of Jatropha curcas, Calophyllum inophyllum, and Ceiba pentandra oils, focusing on developing a unified set of process conditions for effectives conversion. The response surface methodology (RSM), a nonlinear regression approach, was employed to optimize the transesterification process, aiming to simulate and apply the same process parameters across all three oils. Five key factors affecting the conversion of biodiesel: molar ratio, potassium hydroxide, temperature, time, and speed agitation, using two-stage analysis of variance. The optimal experimental conditions for the transesterification process were 0.5 wt% of potassium hydroxide catalyst, a temperature at 50 °C, molar ratio of 9:1, time of reaction at 60 min, and agitation speed of 811 rpm. Under these optimal conditions, >90 % biodiesel yield was obtained. The fuel properties of the biodiesel were evaluated and found to meet ASTM D6751 standards, exhibiting characteristics comparable to conventional diesel. These findings demonstrate the feasibility of using non-edible oils under a single optimized process, paving the way for cost-effective and scalable biodiesel production suitable for compression ignition engines.http://www.sciencedirect.com/science/article/pii/S2590123025003706BiodieselCalophyllum inophyllumCeiba pentandraDesign of experimentJatropha curcasOptimization
spellingShingle Jassinnee Milano
Mei Yin Ong
Sieh Kiong Tiong
F. Ideris
A.S. Silitonga
A.H. Sebayang
Chung Hong Tan
I.M.R. Fattah
Zahra Fona
Nazia Hossain
A comparative study of the production of methyl esters from non-edible oils as potential feedstocks: Process optimization and two-step biodiesel characterization
Results in Engineering
Biodiesel
Calophyllum inophyllum
Ceiba pentandra
Design of experiment
Jatropha curcas
Optimization
title A comparative study of the production of methyl esters from non-edible oils as potential feedstocks: Process optimization and two-step biodiesel characterization
title_full A comparative study of the production of methyl esters from non-edible oils as potential feedstocks: Process optimization and two-step biodiesel characterization
title_fullStr A comparative study of the production of methyl esters from non-edible oils as potential feedstocks: Process optimization and two-step biodiesel characterization
title_full_unstemmed A comparative study of the production of methyl esters from non-edible oils as potential feedstocks: Process optimization and two-step biodiesel characterization
title_short A comparative study of the production of methyl esters from non-edible oils as potential feedstocks: Process optimization and two-step biodiesel characterization
title_sort comparative study of the production of methyl esters from non edible oils as potential feedstocks process optimization and two step biodiesel characterization
topic Biodiesel
Calophyllum inophyllum
Ceiba pentandra
Design of experiment
Jatropha curcas
Optimization
url http://www.sciencedirect.com/science/article/pii/S2590123025003706
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