NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordina...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2020-01-01
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| Series: | Journal of Engineering Studies and Research |
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| Online Access: | https://jesr.ub.ro/index.php/1/article/view/2 |
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| author | BASSENE SEYDOU SEMBENE BOYE MOUHAMADOU SIDIBE MAMADOU DIOP LIBASSE |
| author_facet | BASSENE SEYDOU SEMBENE BOYE MOUHAMADOU SIDIBE MAMADOU DIOP LIBASSE |
| author_sort | BASSENE SEYDOU |
| collection | DOAJ |
| description |
Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordinating ligand, the environments around the tin (IV) centers being octahedral or trigonal bipyramidal. In Me4N(SnPh2)2(H2PO2)2Cl3 and Cl2Sn(H2PO2)2NMe4H2PO2, the cation is involved in electrostatic interactions with the anions.
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| format | Article |
| id | doaj-art-4c0aaaf6691e41d4b535aa348d037db3 |
| institution | Kabale University |
| issn | 2068-7559 2344-4932 |
| language | English |
| publishDate | 2020-01-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj-art-4c0aaaf6691e41d4b535aa348d037db32025-02-09T11:37:43ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322020-01-01261NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDYBASSENE SEYDOU0SEMBENE BOYE MOUHAMADOU1SIDIBE MAMADOU2DIOP LIBASSE3Department of Chemistry, Faculty of Science and Technology, Laboratory of Mineral and Analytical Chemistry, University Cheikh Anta DIOP, Dakar, SenegalDepartment of Physics Chemistry, Faculty of Sciences and Technology of Education and Training, University Cheikh Anta Diop, Boulevard Habib Bourguiba BP 5036 Fann-Dakar, SenegalDepartment of Chemistry, Faculty of Science and Technology, Laboratory of Mineral and Analytical Chemistry, University Cheikh Anta DIOP, Dakar, SenegalDepartment of Chemistry, Faculty of Science and Technology, Laboratory of Mineral and Analytical Chemistry, University Cheikh Anta DIOP, Dakar, Senegal Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordinating ligand, the environments around the tin (IV) centers being octahedral or trigonal bipyramidal. In Me4N(SnPh2)2(H2PO2)2Cl3 and Cl2Sn(H2PO2)2NMe4H2PO2, the cation is involved in electrostatic interactions with the anions. https://jesr.ub.ro/index.php/1/article/view/2bridging aniondiscrete or two metallic components structureselectrostatic interactionsoctahedral or trigonal bipyramidal environments |
| spellingShingle | BASSENE SEYDOU SEMBENE BOYE MOUHAMADOU SIDIBE MAMADOU DIOP LIBASSE NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY Journal of Engineering Studies and Research bridging anion discrete or two metallic components structures electrostatic interactions octahedral or trigonal bipyramidal environments |
| title | NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY |
| title_full | NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY |
| title_fullStr | NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY |
| title_full_unstemmed | NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY |
| title_short | NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY |
| title_sort | new phosphinato organo and halotin iv derivatives adducts and complexes synthesis and spectroscopic study |
| topic | bridging anion discrete or two metallic components structures electrostatic interactions octahedral or trigonal bipyramidal environments |
| url | https://jesr.ub.ro/index.php/1/article/view/2 |
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