Investigation of the Effect of Aerosolized TiO2 Nanoparticles on the NO2 Concentrations under UVA Exposure

Abstract Engineered nanomaterials (ENM) are utilized and produced during many engineering processes. However, they may generate airborne nanoparticles during different phases of their life cycles. TiO2, which is known for its photocatalytic properties, especially in terms of degrading NO2, is one of...

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Main Authors: Ali Mohamadi Nasrabadi, Ana Maria Todea, Carmen Wolf, Tolga Demirel, David Habryka, Christof Asbach
Format: Article
Language:English
Published: Springer 2021-04-01
Series:Aerosol and Air Quality Research
Subjects:
Online Access:https://doi.org/10.4209/aaqr.200612
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author Ali Mohamadi Nasrabadi
Ana Maria Todea
Carmen Wolf
Tolga Demirel
David Habryka
Christof Asbach
author_facet Ali Mohamadi Nasrabadi
Ana Maria Todea
Carmen Wolf
Tolga Demirel
David Habryka
Christof Asbach
author_sort Ali Mohamadi Nasrabadi
collection DOAJ
description Abstract Engineered nanomaterials (ENM) are utilized and produced during many engineering processes. However, they may generate airborne nanoparticles during different phases of their life cycles. TiO2, which is known for its photocatalytic properties, especially in terms of degrading NO2, is one of the most widely produced ENM. Ambient NO2 stems mainly from vehicular and industrial combustion processes and potentially harms human health upon inhalation. This study investigated the photocatalytic reduction of NO2 due to varying concentrations of aerosolized TiO2 nanoparticles during varying levels of ultraviolet A (UVA) exposure. Additionally, we evaluated the effects of low (5%), moderate (35%), and high (70%) relative humidity. Our results demonstrated that the decrease in NO2 depended on both the TiO2 concentration and the UVA intensity. However, when the former was high (> 3.23E+06 cm–3), the contribution of the latter was negligible. On the other hand, when the latter was high, the influence of the former was minimal. Furthermore, as the UVA exposure increased in duration, its effect became dominant over that of the TiO2 concentration. Finally, we found the relative humidity to be an insignificant factor during conditions with strong UVA (6328 W s m–2).
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spelling doaj-art-4ca060e53c0247da84bbd2f2e95357752025-02-09T12:19:51ZengSpringerAerosol and Air Quality Research1680-85842071-14092021-04-0121611410.4209/aaqr.200612Investigation of the Effect of Aerosolized TiO2 Nanoparticles on the NO2 Concentrations under UVA ExposureAli Mohamadi Nasrabadi0Ana Maria Todea1Carmen Wolf2Tolga Demirel3David Habryka4Christof Asbach5Air Quality & Filtration Unit, Institute of Energy and Environmental Technology e. V. (IUTA)Air Quality & Filtration Unit, Institute of Energy and Environmental Technology e. V. (IUTA)Air Quality & Filtration Unit, Institute of Energy and Environmental Technology e. V. (IUTA)Air Quality & Filtration Unit, Institute of Energy and Environmental Technology e. V. (IUTA)Air Quality & Filtration Unit, Institute of Energy and Environmental Technology e. V. (IUTA)Air Quality & Filtration Unit, Institute of Energy and Environmental Technology e. V. (IUTA)Abstract Engineered nanomaterials (ENM) are utilized and produced during many engineering processes. However, they may generate airborne nanoparticles during different phases of their life cycles. TiO2, which is known for its photocatalytic properties, especially in terms of degrading NO2, is one of the most widely produced ENM. Ambient NO2 stems mainly from vehicular and industrial combustion processes and potentially harms human health upon inhalation. This study investigated the photocatalytic reduction of NO2 due to varying concentrations of aerosolized TiO2 nanoparticles during varying levels of ultraviolet A (UVA) exposure. Additionally, we evaluated the effects of low (5%), moderate (35%), and high (70%) relative humidity. Our results demonstrated that the decrease in NO2 depended on both the TiO2 concentration and the UVA intensity. However, when the former was high (> 3.23E+06 cm–3), the contribution of the latter was negligible. On the other hand, when the latter was high, the influence of the former was minimal. Furthermore, as the UVA exposure increased in duration, its effect became dominant over that of the TiO2 concentration. Finally, we found the relative humidity to be an insignificant factor during conditions with strong UVA (6328 W s m–2).https://doi.org/10.4209/aaqr.200612TiO2 aerosolized nanoparticlesNO2 reductionUVA exposureUptake coefficient
spellingShingle Ali Mohamadi Nasrabadi
Ana Maria Todea
Carmen Wolf
Tolga Demirel
David Habryka
Christof Asbach
Investigation of the Effect of Aerosolized TiO2 Nanoparticles on the NO2 Concentrations under UVA Exposure
Aerosol and Air Quality Research
TiO2 aerosolized nanoparticles
NO2 reduction
UVA exposure
Uptake coefficient
title Investigation of the Effect of Aerosolized TiO2 Nanoparticles on the NO2 Concentrations under UVA Exposure
title_full Investigation of the Effect of Aerosolized TiO2 Nanoparticles on the NO2 Concentrations under UVA Exposure
title_fullStr Investigation of the Effect of Aerosolized TiO2 Nanoparticles on the NO2 Concentrations under UVA Exposure
title_full_unstemmed Investigation of the Effect of Aerosolized TiO2 Nanoparticles on the NO2 Concentrations under UVA Exposure
title_short Investigation of the Effect of Aerosolized TiO2 Nanoparticles on the NO2 Concentrations under UVA Exposure
title_sort investigation of the effect of aerosolized tio2 nanoparticles on the no2 concentrations under uva exposure
topic TiO2 aerosolized nanoparticles
NO2 reduction
UVA exposure
Uptake coefficient
url https://doi.org/10.4209/aaqr.200612
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