Identifying the color and absorption band properties of Fe oxides in Danxia red beds by the visible diffuse reflectance spectrum

Abstract This study investigates the Danxia Basin, the place where Danxia landforms were first named, by employing diffuse reflectance spectroscopy to analyze samples from various hue sequences of red beds. The colors of the Danxia red beds were precisely and quantitatively analyzed using the CIE co...

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Main Authors: Wang He, Zhijun Yang, Hongwei Li
Format: Article
Language:English
Published: Nature Portfolio 2025-02-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-025-87913-9
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author Wang He
Zhijun Yang
Hongwei Li
author_facet Wang He
Zhijun Yang
Hongwei Li
author_sort Wang He
collection DOAJ
description Abstract This study investigates the Danxia Basin, the place where Danxia landforms were first named, by employing diffuse reflectance spectroscopy to analyze samples from various hue sequences of red beds. The colors of the Danxia red beds were precisely and quantitatively analyzed using the CIE color space and the Munsell color system. The raw spectra of the samples were then transformed using the second derivative of the Kubelka–Munk function and continuum removal techniques to perform spectral analysis, aiming to elucidate the absorption characteristics of Fe oxides and their influence on the coloration of the Danxia red beds. The results show that the Munsell hues of the Danxia red beds span from 6.5R to 9YR, while powdered samples exhibit a slight yellow shift, ranging from 2.5YR to 0.1Y, with increased chroma and significantly higher lightness. Fe oxides display three main absorption bands in the visible spectrum: (4E; 4A1) ← 6A1, 4T2 ← 6A1, and 2(4T1)  ← 2(6A1) (EPT). Among these, the EPT band plays a pivotal role in determining the color. Since the Fe oxides in the Danxia red beds are predominantly composed of hematite with minor goethite, the EPT (Hem) absorption band is the most prominent, occurring between 526 and 544 nm. While the CIE color space offers superior precision for color measurement and analysis, the Munsell system provides ease of description. Therefore, a combination of both systems is recommended for practical applications.
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spelling doaj-art-7d6c5eb3453e4501a0a75298a977f1cb2025-02-09T12:37:46ZengNature PortfolioScientific Reports2045-23222025-02-0115111610.1038/s41598-025-87913-9Identifying the color and absorption band properties of Fe oxides in Danxia red beds by the visible diffuse reflectance spectrumWang He0Zhijun Yang1Hongwei Li2School of Earth Science and Engineering, Sun Yat-sen UniversitySchool of Earth Science and Engineering, Sun Yat-sen UniversityGuangdong Geological Survey InstituteAbstract This study investigates the Danxia Basin, the place where Danxia landforms were first named, by employing diffuse reflectance spectroscopy to analyze samples from various hue sequences of red beds. The colors of the Danxia red beds were precisely and quantitatively analyzed using the CIE color space and the Munsell color system. The raw spectra of the samples were then transformed using the second derivative of the Kubelka–Munk function and continuum removal techniques to perform spectral analysis, aiming to elucidate the absorption characteristics of Fe oxides and their influence on the coloration of the Danxia red beds. The results show that the Munsell hues of the Danxia red beds span from 6.5R to 9YR, while powdered samples exhibit a slight yellow shift, ranging from 2.5YR to 0.1Y, with increased chroma and significantly higher lightness. Fe oxides display three main absorption bands in the visible spectrum: (4E; 4A1) ← 6A1, 4T2 ← 6A1, and 2(4T1)  ← 2(6A1) (EPT). Among these, the EPT band plays a pivotal role in determining the color. Since the Fe oxides in the Danxia red beds are predominantly composed of hematite with minor goethite, the EPT (Hem) absorption band is the most prominent, occurring between 526 and 544 nm. While the CIE color space offers superior precision for color measurement and analysis, the Munsell system provides ease of description. Therefore, a combination of both systems is recommended for practical applications.https://doi.org/10.1038/s41598-025-87913-9Danxia landformRed bedsDiffuse reflectance spectrumColor quantificationFe oxides
spellingShingle Wang He
Zhijun Yang
Hongwei Li
Identifying the color and absorption band properties of Fe oxides in Danxia red beds by the visible diffuse reflectance spectrum
Scientific Reports
Danxia landform
Red beds
Diffuse reflectance spectrum
Color quantification
Fe oxides
title Identifying the color and absorption band properties of Fe oxides in Danxia red beds by the visible diffuse reflectance spectrum
title_full Identifying the color and absorption band properties of Fe oxides in Danxia red beds by the visible diffuse reflectance spectrum
title_fullStr Identifying the color and absorption band properties of Fe oxides in Danxia red beds by the visible diffuse reflectance spectrum
title_full_unstemmed Identifying the color and absorption band properties of Fe oxides in Danxia red beds by the visible diffuse reflectance spectrum
title_short Identifying the color and absorption band properties of Fe oxides in Danxia red beds by the visible diffuse reflectance spectrum
title_sort identifying the color and absorption band properties of fe oxides in danxia red beds by the visible diffuse reflectance spectrum
topic Danxia landform
Red beds
Diffuse reflectance spectrum
Color quantification
Fe oxides
url https://doi.org/10.1038/s41598-025-87913-9
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