NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES
Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl a...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017-06-01
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| Series: | Journal of Engineering Studies and Research |
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| Online Access: | https://jesr.ub.ro/index.php/1/article/view/81 |
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| author | WALY DIALLO LIBASSE DIOP |
| author_facet | WALY DIALLO LIBASSE DIOP |
| author_sort | WALY DIALLO |
| collection | DOAJ |
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Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl and methyl substituants occupying equatorial positions, the selenate anion behaving as a bridging bidentate ligand and occupying the apical positions. When cations are involved, supramolecular architectures may be obtained.
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| format | Article |
| id | doaj-art-7eab73966d3f4abc9afe3cb5b0f5ec86 |
| institution | Kabale University |
| issn | 2068-7559 2344-4932 |
| language | English |
| publishDate | 2017-06-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj-art-7eab73966d3f4abc9afe3cb5b0f5ec862025-02-09T11:38:05ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322017-06-01232NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIESWALY DIALLO0LIBASSE DIOP1Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, SénégalUniversité Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl and methyl substituants occupying equatorial positions, the selenate anion behaving as a bridging bidentate ligand and occupying the apical positions. When cations are involved, supramolecular architectures may be obtained. https://jesr.ub.ro/index.php/1/article/view/81bridging anionderivativessupramolecular architecturestrans trigonal bipyramidal environmenttriorganotin (IV) residues |
| spellingShingle | WALY DIALLO LIBASSE DIOP NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES Journal of Engineering Studies and Research bridging anion derivatives supramolecular architectures trans trigonal bipyramidal environment triorganotin (IV) residues |
| title | NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
| title_full | NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
| title_fullStr | NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
| title_full_unstemmed | NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
| title_short | NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
| title_sort | new selenato triphenyltin iv and trimethyltin iv derivatives synthesis infrared and nmr studies |
| topic | bridging anion derivatives supramolecular architectures trans trigonal bipyramidal environment triorganotin (IV) residues |
| url | https://jesr.ub.ro/index.php/1/article/view/81 |
| work_keys_str_mv | AT walydiallo newselenatotriphenyltinivandtrimethyltinivderivativessynthesisinfraredandnmrstudies AT libassediop newselenatotriphenyltinivandtrimethyltinivderivativessynthesisinfraredandnmrstudies |