NEW TETRANUCLEAR AND MONONUCLEAR OXALATO ORGANOTIN (IV) COMPLEXES WITH MONOCYCLOHEXYLAMMONIUM AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY
Eight new adducts and derivatives have been synthesized and studied by infrared. Discrete, layered or infinite chain structures are suggested with an oxalate behaving as a monodentate, bidentate, monochelating or bichelating ligand, the environment around the tin centres being tetrahedral, cis trig...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017-12-01
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| Series: | Journal of Engineering Studies and Research |
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| Online Access: | https://jesr.ub.ro/index.php/1/article/view/71 |
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| _version_ | 1823863610954219520 |
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| author | MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP |
| author_facet | MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP |
| author_sort | MODOU SARR |
| collection | DOAJ |
| description |
Eight new adducts and derivatives have been synthesized and studied by infrared. Discrete, layered or infinite chain structures are suggested with an oxalate behaving as a monodentate, bidentate, monochelating or bichelating ligand, the environment around the tin centres being tetrahedral, cis trigonal bipyramidal or octahedral. In all the studied compounds, supramolecular architectures may be obtained when intermolecular hydrogen bonds are considered.
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| format | Article |
| id | doaj-art-80201ee79d0546279cc320fe7ea5f885 |
| institution | Kabale University |
| issn | 2068-7559 2344-4932 |
| language | English |
| publishDate | 2017-12-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj-art-80201ee79d0546279cc320fe7ea5f8852025-02-09T11:38:00ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322017-12-01234NEW TETRANUCLEAR AND MONONUCLEAR OXALATO ORGANOTIN (IV) COMPLEXES WITH MONOCYCLOHEXYLAMMONIUM AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDYMODOU SARR0AMINATA DIASSE-SARR1LIBASSE DIOP2Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal Eight new adducts and derivatives have been synthesized and studied by infrared. Discrete, layered or infinite chain structures are suggested with an oxalate behaving as a monodentate, bidentate, monochelating or bichelating ligand, the environment around the tin centres being tetrahedral, cis trigonal bipyramidal or octahedral. In all the studied compounds, supramolecular architectures may be obtained when intermolecular hydrogen bonds are considered. https://jesr.ub.ro/index.php/1/article/view/71monodentatebidentatebichelatingmonochelating oxalateinfrared, hydrogen bondsSnPh |
| spellingShingle | MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP NEW TETRANUCLEAR AND MONONUCLEAR OXALATO ORGANOTIN (IV) COMPLEXES WITH MONOCYCLOHEXYLAMMONIUM AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY Journal of Engineering Studies and Research monodentate bidentate bichelating monochelating oxalate infrared, hydrogen bonds SnPh |
| title | NEW TETRANUCLEAR AND MONONUCLEAR OXALATO ORGANOTIN (IV) COMPLEXES WITH MONOCYCLOHEXYLAMMONIUM AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY |
| title_full | NEW TETRANUCLEAR AND MONONUCLEAR OXALATO ORGANOTIN (IV) COMPLEXES WITH MONOCYCLOHEXYLAMMONIUM AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY |
| title_fullStr | NEW TETRANUCLEAR AND MONONUCLEAR OXALATO ORGANOTIN (IV) COMPLEXES WITH MONOCYCLOHEXYLAMMONIUM AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY |
| title_full_unstemmed | NEW TETRANUCLEAR AND MONONUCLEAR OXALATO ORGANOTIN (IV) COMPLEXES WITH MONOCYCLOHEXYLAMMONIUM AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY |
| title_short | NEW TETRANUCLEAR AND MONONUCLEAR OXALATO ORGANOTIN (IV) COMPLEXES WITH MONOCYCLOHEXYLAMMONIUM AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY |
| title_sort | new tetranuclear and mononuclear oxalato organotin iv complexes with monocyclohexylammonium as adverse cation synthesis and infrared study |
| topic | monodentate bidentate bichelating monochelating oxalate infrared, hydrogen bonds SnPh |
| url | https://jesr.ub.ro/index.php/1/article/view/71 |
| work_keys_str_mv | AT modousarr newtetranuclearandmononuclearoxalatoorganotinivcomplexeswithmonocyclohexylammoniumasadversecationsynthesisandinfraredstudy AT aminatadiassesarr newtetranuclearandmononuclearoxalatoorganotinivcomplexeswithmonocyclohexylammoniumasadversecationsynthesisandinfraredstudy AT libassediop newtetranuclearandmononuclearoxalatoorganotinivcomplexeswithmonocyclohexylammoniumasadversecationsynthesisandinfraredstudy |