Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots

This work reports synthesis of core-shell CdSe/CdS/ZnS quantum dots (QD) and the amorphous β-diketonate Eu(CPDK3–5)3bpy17–17 complex. Oleic and stearic acids were used to stabilize colloid nanoparticles and disperse them in organic solvents. Hybrid films of polymethyl methacrylate with various mass...

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Main Authors: Ruzanna M. Ziyatdinova, Andrey A. Knyazev, Dmitriy O. Sagdeev, Yuriy G. Galyametdinov
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-12-01
Series:Supramolecular Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2667240525000078
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author Ruzanna M. Ziyatdinova
Andrey A. Knyazev
Dmitriy O. Sagdeev
Yuriy G. Galyametdinov
author_facet Ruzanna M. Ziyatdinova
Andrey A. Knyazev
Dmitriy O. Sagdeev
Yuriy G. Galyametdinov
author_sort Ruzanna M. Ziyatdinova
collection DOAJ
description This work reports synthesis of core-shell CdSe/CdS/ZnS quantum dots (QD) and the amorphous β-diketonate Eu(CPDK3–5)3bpy17–17 complex. Oleic and stearic acids were used to stabilize colloid nanoparticles and disperse them in organic solvents. Hybrid films of polymethyl methacrylate with various mass ratios of doped quantum dots and europium complexes were produced by spin-coating. The application potential of these materials as ratiometric temperature sensors was analyzed. The produced films demonstrated the highest sensitivity of photoluminescence in the temperature range of 298 – 393 K among other known analogues.
format Article
id doaj-art-84c5d6ec545243b395b0074c0de89295
institution Kabale University
issn 2667-2405
language English
publishDate 2025-12-01
publisher KeAi Communications Co., Ltd.
record_format Article
series Supramolecular Materials
spelling doaj-art-84c5d6ec545243b395b0074c0de892952025-02-11T04:35:34ZengKeAi Communications Co., Ltd.Supramolecular Materials2667-24052025-12-014100098Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dotsRuzanna M. Ziyatdinova0Andrey A. Knyazev1Dmitriy O. Sagdeev2Yuriy G. Galyametdinov3Kazan National Research Technological University, Kazan, RussiaCorresponding author.; Kazan National Research Technological University, Kazan, RussiaKazan National Research Technological University, Kazan, RussiaKazan National Research Technological University, Kazan, RussiaThis work reports synthesis of core-shell CdSe/CdS/ZnS quantum dots (QD) and the amorphous β-diketonate Eu(CPDK3–5)3bpy17–17 complex. Oleic and stearic acids were used to stabilize colloid nanoparticles and disperse them in organic solvents. Hybrid films of polymethyl methacrylate with various mass ratios of doped quantum dots and europium complexes were produced by spin-coating. The application potential of these materials as ratiometric temperature sensors was analyzed. The produced films demonstrated the highest sensitivity of photoluminescence in the temperature range of 298 – 393 K among other known analogues.http://www.sciencedirect.com/science/article/pii/S2667240525000078Ln(III) complexesQuantum dotsPMMAPhotoluminescenceLuminescent thermal sensor
spellingShingle Ruzanna M. Ziyatdinova
Andrey A. Knyazev
Dmitriy O. Sagdeev
Yuriy G. Galyametdinov
Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots
Supramolecular Materials
Ln(III) complexes
Quantum dots
PMMA
Photoluminescence
Luminescent thermal sensor
title Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots
title_full Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots
title_fullStr Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots
title_full_unstemmed Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots
title_short Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots
title_sort ratiometric luminescent temperature sensor based on amorphous complex of europium iii and quantum dots
topic Ln(III) complexes
Quantum dots
PMMA
Photoluminescence
Luminescent thermal sensor
url http://www.sciencedirect.com/science/article/pii/S2667240525000078
work_keys_str_mv AT ruzannamziyatdinova ratiometricluminescenttemperaturesensorbasedonamorphouscomplexofeuropiumiiiandquantumdots
AT andreyaknyazev ratiometricluminescenttemperaturesensorbasedonamorphouscomplexofeuropiumiiiandquantumdots
AT dmitriyosagdeev ratiometricluminescenttemperaturesensorbasedonamorphouscomplexofeuropiumiiiandquantumdots
AT yuriyggalyametdinov ratiometricluminescenttemperaturesensorbasedonamorphouscomplexofeuropiumiiiandquantumdots