About polyhedrane “cages” and their doubtful supramolecular lodging capacity: a demonstration by the absurd and a plea for free expression in scientific journals
Polyhedral “cage” compounds such as cubane, adamantane, dodecahedrane, and their perfluorinated analogs, despite their appellation and standard representation, show little aptitude for supramolecular host–guest chemistry. The mere inspection of covalent and van der Waals atomic radii should convince...
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| Format: | Article |
| Language: | English |
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Académie des sciences
2024-05-01
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| Series: | Comptes Rendus. Chimie |
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| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.288/ |
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| author | Riess, Jean G. |
| author_facet | Riess, Jean G. |
| author_sort | Riess, Jean G. |
| collection | DOAJ |
| description | Polyhedral “cage” compounds such as cubane, adamantane, dodecahedrane, and their perfluorinated analogs, despite their appellation and standard representation, show little aptitude for supramolecular host–guest chemistry. The mere inspection of covalent and van der Waals atomic radii should convince the most dubious Reader of that. Yet, some perplexing patents claim the insertion of oxygen molecules within perfluorohexamethylenetetramine, a (not yet documented) compound that is structurally related to perfluoroadamantane. The question of the publishability of a skeptical opinion on such techno-legal documents in scientific journals is raised. Further considerations relate to didactic approaches, correction of misconceptions, scientific edition challenges, publication ethics, societal awareness, scientists’ accountability, and include a plea for freedom of expression, increased transparency in the article reviewing process, and enhanced communication between, editors, referees, and authors. The referees’ comments on this opinion paper and author’s responses are provided as supplementary data. |
| format | Article |
| id | doaj-art-8d754880cabc4681b476de52947b6861 |
| institution | Kabale University |
| issn | 1878-1543 |
| language | English |
| publishDate | 2024-05-01 |
| publisher | Académie des sciences |
| record_format | Article |
| series | Comptes Rendus. Chimie |
| spelling | doaj-art-8d754880cabc4681b476de52947b68612025-02-07T13:39:46ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432024-05-0127G111312710.5802/crchim.28810.5802/crchim.288About polyhedrane “cages” and their doubtful supramolecular lodging capacity: a demonstration by the absurd and a plea for free expression in scientific journalsRiess, Jean G.0https://orcid.org/0000-0002-8937-7327Harangoutte, Ste-Croix-aux-Mines 68160, FrancePolyhedral “cage” compounds such as cubane, adamantane, dodecahedrane, and their perfluorinated analogs, despite their appellation and standard representation, show little aptitude for supramolecular host–guest chemistry. The mere inspection of covalent and van der Waals atomic radii should convince the most dubious Reader of that. Yet, some perplexing patents claim the insertion of oxygen molecules within perfluorohexamethylenetetramine, a (not yet documented) compound that is structurally related to perfluoroadamantane. The question of the publishability of a skeptical opinion on such techno-legal documents in scientific journals is raised. Further considerations relate to didactic approaches, correction of misconceptions, scientific edition challenges, publication ethics, societal awareness, scientists’ accountability, and include a plea for freedom of expression, increased transparency in the article reviewing process, and enhanced communication between, editors, referees, and authors. The referees’ comments on this opinion paper and author’s responses are provided as supplementary data.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.288/Cage compoundHost–guest chemistryNon-covalent bindingFluorocarbonOxygen carrierPublication ethicsScience and society |
| spellingShingle | Riess, Jean G. About polyhedrane “cages” and their doubtful supramolecular lodging capacity: a demonstration by the absurd and a plea for free expression in scientific journals Comptes Rendus. Chimie Cage compound Host–guest chemistry Non-covalent binding Fluorocarbon Oxygen carrier Publication ethics Science and society |
| title | About polyhedrane “cages” and their doubtful supramolecular lodging capacity: a demonstration by the absurd and a plea for free expression in scientific journals |
| title_full | About polyhedrane “cages” and their doubtful supramolecular lodging capacity: a demonstration by the absurd and a plea for free expression in scientific journals |
| title_fullStr | About polyhedrane “cages” and their doubtful supramolecular lodging capacity: a demonstration by the absurd and a plea for free expression in scientific journals |
| title_full_unstemmed | About polyhedrane “cages” and their doubtful supramolecular lodging capacity: a demonstration by the absurd and a plea for free expression in scientific journals |
| title_short | About polyhedrane “cages” and their doubtful supramolecular lodging capacity: a demonstration by the absurd and a plea for free expression in scientific journals |
| title_sort | about polyhedrane cages and their doubtful supramolecular lodging capacity a demonstration by the absurd and a plea for free expression in scientific journals |
| topic | Cage compound Host–guest chemistry Non-covalent binding Fluorocarbon Oxygen carrier Publication ethics Science and society |
| url | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.288/ |
| work_keys_str_mv | AT riessjeang aboutpolyhedranecagesandtheirdoubtfulsupramolecularlodgingcapacityademonstrationbytheabsurdandapleaforfreeexpressioninscientificjournals |