Impact of Ag2O on physical and electrical properties of Li2O-MgO-Bi2O3-SiO2 glass system as promising solid state electrolytes
Abstract The intrinsic aim of this work is to understand the influence of composition change on the physical-electrical parameters of glasses with the composition (20-Y) Li2O-YAg2O–20MgO–10Bi2O3-50SiO2 (Y = 0.25, 0.5, 1.0, 2.0 and 4.0 mol%). The results of the physical parameters indicate a growth i...
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Nature Portfolio
2025-02-01
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| Online Access: | https://doi.org/10.1038/s41598-025-87463-0 |
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| author | Hany A. Abo-Mosallam Samia E. Ibrahim |
| author_facet | Hany A. Abo-Mosallam Samia E. Ibrahim |
| author_sort | Hany A. Abo-Mosallam |
| collection | DOAJ |
| description | Abstract The intrinsic aim of this work is to understand the influence of composition change on the physical-electrical parameters of glasses with the composition (20-Y) Li2O-YAg2O–20MgO–10Bi2O3-50SiO2 (Y = 0.25, 0.5, 1.0, 2.0 and 4.0 mol%). The results of the physical parameters indicate a growth in the strength of the glass structure with the increase replacement of Li2O by Ag2O. However, the decrease in loss factor ε″, and AC conductivity σ ac of glasses may be attributed to the decrease in the space charge polarization (scp). AC conductivities exhibit simple power law variation. The s values essentially lie in the range of 0.67–0.92, which is typical of conductors in Jonscher regime. Dielectric properties (constant ε′, loss ε″ and ac conductivity σac, over a range of frequency 100–100 kHz and temperature RT (Room Temperature)–200 °C and frequency exponent s) of these glasses have been studied The results indicate a great potential of the prepared glasses as promising materials that can be used for solid state electrolytes. |
| format | Article |
| id | doaj-art-9f3cb246c5074442933f4f4e6274689e |
| institution | Kabale University |
| issn | 2045-2322 |
| language | English |
| publishDate | 2025-02-01 |
| publisher | Nature Portfolio |
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| spelling | doaj-art-9f3cb246c5074442933f4f4e6274689e2025-02-09T12:29:09ZengNature PortfolioScientific Reports2045-23222025-02-0115111510.1038/s41598-025-87463-0Impact of Ag2O on physical and electrical properties of Li2O-MgO-Bi2O3-SiO2 glass system as promising solid state electrolytesHany A. Abo-Mosallam0Samia E. Ibrahim1Glass Research Department, National Research CentrePhysics Department, Faculty of Science, Menoufia UniversityAbstract The intrinsic aim of this work is to understand the influence of composition change on the physical-electrical parameters of glasses with the composition (20-Y) Li2O-YAg2O–20MgO–10Bi2O3-50SiO2 (Y = 0.25, 0.5, 1.0, 2.0 and 4.0 mol%). The results of the physical parameters indicate a growth in the strength of the glass structure with the increase replacement of Li2O by Ag2O. However, the decrease in loss factor ε″, and AC conductivity σ ac of glasses may be attributed to the decrease in the space charge polarization (scp). AC conductivities exhibit simple power law variation. The s values essentially lie in the range of 0.67–0.92, which is typical of conductors in Jonscher regime. Dielectric properties (constant ε′, loss ε″ and ac conductivity σac, over a range of frequency 100–100 kHz and temperature RT (Room Temperature)–200 °C and frequency exponent s) of these glasses have been studied The results indicate a great potential of the prepared glasses as promising materials that can be used for solid state electrolytes.https://doi.org/10.1038/s41598-025-87463-0GlassAg2OBismuth-silicateStructureElectricalSolid electrolytes |
| spellingShingle | Hany A. Abo-Mosallam Samia E. Ibrahim Impact of Ag2O on physical and electrical properties of Li2O-MgO-Bi2O3-SiO2 glass system as promising solid state electrolytes Scientific Reports Glass Ag2O Bismuth-silicate Structure Electrical Solid electrolytes |
| title | Impact of Ag2O on physical and electrical properties of Li2O-MgO-Bi2O3-SiO2 glass system as promising solid state electrolytes |
| title_full | Impact of Ag2O on physical and electrical properties of Li2O-MgO-Bi2O3-SiO2 glass system as promising solid state electrolytes |
| title_fullStr | Impact of Ag2O on physical and electrical properties of Li2O-MgO-Bi2O3-SiO2 glass system as promising solid state electrolytes |
| title_full_unstemmed | Impact of Ag2O on physical and electrical properties of Li2O-MgO-Bi2O3-SiO2 glass system as promising solid state electrolytes |
| title_short | Impact of Ag2O on physical and electrical properties of Li2O-MgO-Bi2O3-SiO2 glass system as promising solid state electrolytes |
| title_sort | impact of ag2o on physical and electrical properties of li2o mgo bi2o3 sio2 glass system as promising solid state electrolytes |
| topic | Glass Ag2O Bismuth-silicate Structure Electrical Solid electrolytes |
| url | https://doi.org/10.1038/s41598-025-87463-0 |
| work_keys_str_mv | AT hanyaabomosallam impactofag2oonphysicalandelectricalpropertiesofli2omgobi2o3sio2glasssystemaspromisingsolidstateelectrolytes AT samiaeibrahim impactofag2oonphysicalandelectricalpropertiesofli2omgobi2o3sio2glasssystemaspromisingsolidstateelectrolytes |