Dye adsorption on fish scale biosorbent from tannery wastewater

In leather processing, dyeing is an essential operation to make it attractive for fashion style. Emitted dyeing wastewater contains dye, fixing agent, syntan, resin, and fat. Dye removal from real wastewater is challenging because it includes other matrices. Dyes in wastewater have an adverse influe...

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Main Authors: Md. Abul Hashem, Forhad Ahammad, Bishwajit Chandra Das, Eshtiyaq Tauhid Enan, Modinatul Maoya, Mohammad Jakir Hossain Khan, Md. Mukimujjaman Miem
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Next Sustainability
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Online Access:http://www.sciencedirect.com/science/article/pii/S2949823625000157
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author Md. Abul Hashem
Forhad Ahammad
Bishwajit Chandra Das
Eshtiyaq Tauhid Enan
Modinatul Maoya
Mohammad Jakir Hossain Khan
Md. Mukimujjaman Miem
author_facet Md. Abul Hashem
Forhad Ahammad
Bishwajit Chandra Das
Eshtiyaq Tauhid Enan
Modinatul Maoya
Mohammad Jakir Hossain Khan
Md. Mukimujjaman Miem
author_sort Md. Abul Hashem
collection DOAJ
description In leather processing, dyeing is an essential operation to make it attractive for fashion style. Emitted dyeing wastewater contains dye, fixing agent, syntan, resin, and fat. Dye removal from real wastewater is challenging because it includes other matrices. Dyes in wastewater have an adverse influence on the aquatic ecosystem. This research concerns the suitability of fish biowaste adsorbent for dye removal from tannery wastewater. The obtained biosorbent was analyzed through Fourier Transform Infrared (FTIR) Spectroscopy, pH point of zero charge (pHpzc), Energy Dispersive Spectroscopy (EDS), and Scanning Electron Microscope (SEM). The dye removal efficiency was evaluated by monitoring the biosorbent dose, settling time, stirring time, and temperature effect. The dye adsorption mechanism was characterized using Freundlich and Langmuir’s regression models. The maximum dye removal efficiency (81.8 %) was achieved with a 2 g biosorbent dose per 50 mL of wastewater, 25 min stirring time, 30°C temperature, and 20 h settling time at pH 4.8. The adsorption kinetics demonstrated that the pseudo-second-order reaction (PSO) model shows a good regression coefficient (R2=0.94). The removal of Total Dissolved Solids (TDS), Biochemical Oxygen Demand (BOD), turbidity, and Chemical Oxygen Demand (COD) were 39.8 %, 69.7 %, 48.1 %, and 90.1 %, respectively. Hence, the fish scale biosorbent could be a feasible adsorbent for leather dyeing wastewater treatment, and further research can be conducted to explore its potential for large-scale application.
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spelling doaj-art-a2bdb2c004e44b8e87ec50d143793e3c2025-02-12T05:33:14ZengElsevierNext Sustainability2949-82362025-01-016100112Dye adsorption on fish scale biosorbent from tannery wastewaterMd. Abul Hashem0Forhad Ahammad1Bishwajit Chandra Das2Eshtiyaq Tauhid Enan3Modinatul Maoya4Mohammad Jakir Hossain Khan5Md. Mukimujjaman Miem6Department of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, Bangladesh; Corresponding author.Department of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshDepartment of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshDepartment of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshDepartment of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshEngineering Department, Faculty of Marine Technology and Natural Sciences, Klaipeda University, H. Manto 84, Klaipeda 92294, LithuaniaDepartment of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshIn leather processing, dyeing is an essential operation to make it attractive for fashion style. Emitted dyeing wastewater contains dye, fixing agent, syntan, resin, and fat. Dye removal from real wastewater is challenging because it includes other matrices. Dyes in wastewater have an adverse influence on the aquatic ecosystem. This research concerns the suitability of fish biowaste adsorbent for dye removal from tannery wastewater. The obtained biosorbent was analyzed through Fourier Transform Infrared (FTIR) Spectroscopy, pH point of zero charge (pHpzc), Energy Dispersive Spectroscopy (EDS), and Scanning Electron Microscope (SEM). The dye removal efficiency was evaluated by monitoring the biosorbent dose, settling time, stirring time, and temperature effect. The dye adsorption mechanism was characterized using Freundlich and Langmuir’s regression models. The maximum dye removal efficiency (81.8 %) was achieved with a 2 g biosorbent dose per 50 mL of wastewater, 25 min stirring time, 30°C temperature, and 20 h settling time at pH 4.8. The adsorption kinetics demonstrated that the pseudo-second-order reaction (PSO) model shows a good regression coefficient (R2=0.94). The removal of Total Dissolved Solids (TDS), Biochemical Oxygen Demand (BOD), turbidity, and Chemical Oxygen Demand (COD) were 39.8 %, 69.7 %, 48.1 %, and 90.1 %, respectively. Hence, the fish scale biosorbent could be a feasible adsorbent for leather dyeing wastewater treatment, and further research can be conducted to explore its potential for large-scale application.http://www.sciencedirect.com/science/article/pii/S2949823625000157Batch adsorptionDyeingEffluentKineticsPhysicochemical parameters
spellingShingle Md. Abul Hashem
Forhad Ahammad
Bishwajit Chandra Das
Eshtiyaq Tauhid Enan
Modinatul Maoya
Mohammad Jakir Hossain Khan
Md. Mukimujjaman Miem
Dye adsorption on fish scale biosorbent from tannery wastewater
Next Sustainability
Batch adsorption
Dyeing
Effluent
Kinetics
Physicochemical parameters
title Dye adsorption on fish scale biosorbent from tannery wastewater
title_full Dye adsorption on fish scale biosorbent from tannery wastewater
title_fullStr Dye adsorption on fish scale biosorbent from tannery wastewater
title_full_unstemmed Dye adsorption on fish scale biosorbent from tannery wastewater
title_short Dye adsorption on fish scale biosorbent from tannery wastewater
title_sort dye adsorption on fish scale biosorbent from tannery wastewater
topic Batch adsorption
Dyeing
Effluent
Kinetics
Physicochemical parameters
url http://www.sciencedirect.com/science/article/pii/S2949823625000157
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