Dye adsorption on fish scale biosorbent from tannery wastewater
In leather processing, dyeing is an essential operation to make it attractive for fashion style. Emitted dyeing wastewater contains dye, fixing agent, syntan, resin, and fat. Dye removal from real wastewater is challenging because it includes other matrices. Dyes in wastewater have an adverse influe...
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2025-01-01
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author | Md. Abul Hashem Forhad Ahammad Bishwajit Chandra Das Eshtiyaq Tauhid Enan Modinatul Maoya Mohammad Jakir Hossain Khan Md. Mukimujjaman Miem |
author_facet | Md. Abul Hashem Forhad Ahammad Bishwajit Chandra Das Eshtiyaq Tauhid Enan Modinatul Maoya Mohammad Jakir Hossain Khan Md. Mukimujjaman Miem |
author_sort | Md. Abul Hashem |
collection | DOAJ |
description | In leather processing, dyeing is an essential operation to make it attractive for fashion style. Emitted dyeing wastewater contains dye, fixing agent, syntan, resin, and fat. Dye removal from real wastewater is challenging because it includes other matrices. Dyes in wastewater have an adverse influence on the aquatic ecosystem. This research concerns the suitability of fish biowaste adsorbent for dye removal from tannery wastewater. The obtained biosorbent was analyzed through Fourier Transform Infrared (FTIR) Spectroscopy, pH point of zero charge (pHpzc), Energy Dispersive Spectroscopy (EDS), and Scanning Electron Microscope (SEM). The dye removal efficiency was evaluated by monitoring the biosorbent dose, settling time, stirring time, and temperature effect. The dye adsorption mechanism was characterized using Freundlich and Langmuir’s regression models. The maximum dye removal efficiency (81.8 %) was achieved with a 2 g biosorbent dose per 50 mL of wastewater, 25 min stirring time, 30°C temperature, and 20 h settling time at pH 4.8. The adsorption kinetics demonstrated that the pseudo-second-order reaction (PSO) model shows a good regression coefficient (R2=0.94). The removal of Total Dissolved Solids (TDS), Biochemical Oxygen Demand (BOD), turbidity, and Chemical Oxygen Demand (COD) were 39.8 %, 69.7 %, 48.1 %, and 90.1 %, respectively. Hence, the fish scale biosorbent could be a feasible adsorbent for leather dyeing wastewater treatment, and further research can be conducted to explore its potential for large-scale application. |
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id | doaj-art-a2bdb2c004e44b8e87ec50d143793e3c |
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issn | 2949-8236 |
language | English |
publishDate | 2025-01-01 |
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record_format | Article |
series | Next Sustainability |
spelling | doaj-art-a2bdb2c004e44b8e87ec50d143793e3c2025-02-12T05:33:14ZengElsevierNext Sustainability2949-82362025-01-016100112Dye adsorption on fish scale biosorbent from tannery wastewaterMd. Abul Hashem0Forhad Ahammad1Bishwajit Chandra Das2Eshtiyaq Tauhid Enan3Modinatul Maoya4Mohammad Jakir Hossain Khan5Md. Mukimujjaman Miem6Department of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, Bangladesh; Corresponding author.Department of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshDepartment of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshDepartment of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshDepartment of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshEngineering Department, Faculty of Marine Technology and Natural Sciences, Klaipeda University, H. Manto 84, Klaipeda 92294, LithuaniaDepartment of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna 9203, BangladeshIn leather processing, dyeing is an essential operation to make it attractive for fashion style. Emitted dyeing wastewater contains dye, fixing agent, syntan, resin, and fat. Dye removal from real wastewater is challenging because it includes other matrices. Dyes in wastewater have an adverse influence on the aquatic ecosystem. This research concerns the suitability of fish biowaste adsorbent for dye removal from tannery wastewater. The obtained biosorbent was analyzed through Fourier Transform Infrared (FTIR) Spectroscopy, pH point of zero charge (pHpzc), Energy Dispersive Spectroscopy (EDS), and Scanning Electron Microscope (SEM). The dye removal efficiency was evaluated by monitoring the biosorbent dose, settling time, stirring time, and temperature effect. The dye adsorption mechanism was characterized using Freundlich and Langmuir’s regression models. The maximum dye removal efficiency (81.8 %) was achieved with a 2 g biosorbent dose per 50 mL of wastewater, 25 min stirring time, 30°C temperature, and 20 h settling time at pH 4.8. The adsorption kinetics demonstrated that the pseudo-second-order reaction (PSO) model shows a good regression coefficient (R2=0.94). The removal of Total Dissolved Solids (TDS), Biochemical Oxygen Demand (BOD), turbidity, and Chemical Oxygen Demand (COD) were 39.8 %, 69.7 %, 48.1 %, and 90.1 %, respectively. Hence, the fish scale biosorbent could be a feasible adsorbent for leather dyeing wastewater treatment, and further research can be conducted to explore its potential for large-scale application.http://www.sciencedirect.com/science/article/pii/S2949823625000157Batch adsorptionDyeingEffluentKineticsPhysicochemical parameters |
spellingShingle | Md. Abul Hashem Forhad Ahammad Bishwajit Chandra Das Eshtiyaq Tauhid Enan Modinatul Maoya Mohammad Jakir Hossain Khan Md. Mukimujjaman Miem Dye adsorption on fish scale biosorbent from tannery wastewater Next Sustainability Batch adsorption Dyeing Effluent Kinetics Physicochemical parameters |
title | Dye adsorption on fish scale biosorbent from tannery wastewater |
title_full | Dye adsorption on fish scale biosorbent from tannery wastewater |
title_fullStr | Dye adsorption on fish scale biosorbent from tannery wastewater |
title_full_unstemmed | Dye adsorption on fish scale biosorbent from tannery wastewater |
title_short | Dye adsorption on fish scale biosorbent from tannery wastewater |
title_sort | dye adsorption on fish scale biosorbent from tannery wastewater |
topic | Batch adsorption Dyeing Effluent Kinetics Physicochemical parameters |
url | http://www.sciencedirect.com/science/article/pii/S2949823625000157 |
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