Assessment of the applied potential of sludge-derived hydrochar in terms of process parameters and product properties

Hydrothermal carbonization (HTC) is beneficial for the disposal of high-moisture organic waste such as sludge. However, the relationship between HTC parameters and hydrochars has not been fully explored, and most studies have focused on single or dual parameters. This paper systematically studied ho...

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Main Authors: Zhang, Chuang, Wang, Bingyu, Wang, Jixiang, Rong, Shaopeng,  Xie, Huifang, Qu, Hongxia, Feng, Yanfang
Format: Article
Language:English
Published: Académie des sciences 2024-10-01
Series:Comptes Rendus. Chimie
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Online Access:https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.333/
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author Zhang, Chuang
Wang, Bingyu
Wang, Jixiang
Rong, Shaopeng
 Xie, Huifang
Qu, Hongxia
Feng, Yanfang
author_facet Zhang, Chuang
Wang, Bingyu
Wang, Jixiang
Rong, Shaopeng
 Xie, Huifang
Qu, Hongxia
Feng, Yanfang
author_sort Zhang, Chuang
collection DOAJ
description Hydrothermal carbonization (HTC) is beneficial for the disposal of high-moisture organic waste such as sludge. However, the relationship between HTC parameters and hydrochars has not been fully explored, and most studies have focused on single or dual parameters. This paper systematically studied how hydrothermal intensity and solid loading affected the HTC process, hydrochar yield, and composition properties. The results revealed that the organic matter or ash content in sludge was a vital factor affecting the fuel properties of hydrochars. The hydrothermal intensity was a critical process parameter for hydrochars’ structural properties. The solid loading had no apparent effect on hydrochars but had a considerable effect on energy consumption in the HTC process. When the moisture content of sludge was 80.3%, the energy recoverable by hydrochars could be sufficient for the material to be heated up to phase transition. Evaluations of sludge characteristics in different regions and treatment processes were conducted, allowing HTC process parameters to be optimized in correlation with future resource utilization approaches. If the sludge contains a great deal of organic matter and is used as a fuel to generate energy, it can be subjected to a milder hydrothermal intensity like 180–220 °C for 1–2 h. If the heavy metal content in the sludge meets land-use requirements, a more intense hydrothermal intensity may be applied such as 260 °C for 1–4 h. This study provides a reference for the design, optimization, and scaling of HTC for sludge treatment.
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spelling doaj-art-a64f745dfe0d498fb39a446c5bc4c5fd2025-02-07T13:40:47ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432024-10-0111810.5802/crchim.33310.5802/crchim.333Assessment of the applied potential of sludge-derived hydrochar in terms of process parameters and product propertiesZhang, Chuang0Wang, Bingyu1https://orcid.org/0000-0001-5865-4849Wang, Jixiang2Rong, Shaopeng3https://orcid.org/0000-0003-0899-871X Xie, Huifang4https://orcid.org/0000-0001-6082-7112Qu, Hongxia5Feng, Yanfang6https://orcid.org/0000-0001-6251-7660Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, ChinaJiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, ChinaJiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China; Key Laboratory of Agro-Environment in Downstream of Yangtze Plain, National Agricultural Experiment Station for Agricultural Environment, Ministry of Agriculture and Rural Affairs, Institute of Agricultural Resources and Environment, Jiangsu Academy of Agricultural Sciences, Nanjing 210014, ChinaJiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, ChinaJiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, ChinaSchool of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, Jiangsu Province, ChinaKey Laboratory of Agro-Environment in Downstream of Yangtze Plain, National Agricultural Experiment Station for Agricultural Environment, Ministry of Agriculture and Rural Affairs, Institute of Agricultural Resources and Environment, Jiangsu Academy of Agricultural Sciences, Nanjing 210014, ChinaHydrothermal carbonization (HTC) is beneficial for the disposal of high-moisture organic waste such as sludge. However, the relationship between HTC parameters and hydrochars has not been fully explored, and most studies have focused on single or dual parameters. This paper systematically studied how hydrothermal intensity and solid loading affected the HTC process, hydrochar yield, and composition properties. The results revealed that the organic matter or ash content in sludge was a vital factor affecting the fuel properties of hydrochars. The hydrothermal intensity was a critical process parameter for hydrochars’ structural properties. The solid loading had no apparent effect on hydrochars but had a considerable effect on energy consumption in the HTC process. When the moisture content of sludge was 80.3%, the energy recoverable by hydrochars could be sufficient for the material to be heated up to phase transition. Evaluations of sludge characteristics in different regions and treatment processes were conducted, allowing HTC process parameters to be optimized in correlation with future resource utilization approaches. If the sludge contains a great deal of organic matter and is used as a fuel to generate energy, it can be subjected to a milder hydrothermal intensity like 180–220 °C for 1–2 h. If the heavy metal content in the sludge meets land-use requirements, a more intense hydrothermal intensity may be applied such as 260 °C for 1–4 h. This study provides a reference for the design, optimization, and scaling of HTC for sludge treatment.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.333/SludgeHydrothermal carbonizationHydrocharHydrothermal intensitySolid loading
spellingShingle Zhang, Chuang
Wang, Bingyu
Wang, Jixiang
Rong, Shaopeng
 Xie, Huifang
Qu, Hongxia
Feng, Yanfang
Assessment of the applied potential of sludge-derived hydrochar in terms of process parameters and product properties
Comptes Rendus. Chimie
Sludge
Hydrothermal carbonization
Hydrochar
Hydrothermal intensity
Solid loading
title Assessment of the applied potential of sludge-derived hydrochar in terms of process parameters and product properties
title_full Assessment of the applied potential of sludge-derived hydrochar in terms of process parameters and product properties
title_fullStr Assessment of the applied potential of sludge-derived hydrochar in terms of process parameters and product properties
title_full_unstemmed Assessment of the applied potential of sludge-derived hydrochar in terms of process parameters and product properties
title_short Assessment of the applied potential of sludge-derived hydrochar in terms of process parameters and product properties
title_sort assessment of the applied potential of sludge derived hydrochar in terms of process parameters and product properties
topic Sludge
Hydrothermal carbonization
Hydrochar
Hydrothermal intensity
Solid loading
url https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.333/
work_keys_str_mv AT zhangchuang assessmentoftheappliedpotentialofsludgederivedhydrocharintermsofprocessparametersandproductproperties
AT wangbingyu assessmentoftheappliedpotentialofsludgederivedhydrocharintermsofprocessparametersandproductproperties
AT wangjixiang assessmentoftheappliedpotentialofsludgederivedhydrocharintermsofprocessparametersandproductproperties
AT rongshaopeng assessmentoftheappliedpotentialofsludgederivedhydrocharintermsofprocessparametersandproductproperties
AT xiehuifang assessmentoftheappliedpotentialofsludgederivedhydrocharintermsofprocessparametersandproductproperties
AT quhongxia assessmentoftheappliedpotentialofsludgederivedhydrocharintermsofprocessparametersandproductproperties
AT fengyanfang assessmentoftheappliedpotentialofsludgederivedhydrocharintermsofprocessparametersandproductproperties