Wet Deposition and Long-range Transport of Major Ions Related to Snow at Northwestern Himalayas (India)

Abstract The present study was carried out to understand the snow chemistry with special emphasis on the estimation of wet deposition fluxes and transportation of ionic species to the Himalayan regions from December 2015 to March 2017. All the snow samples were collected from three different sites o...

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Main Authors: Anshu Sharma, U. C. Kulshrestha
Format: Article
Language:English
Published: Springer 2020-04-01
Series:Aerosol and Air Quality Research
Subjects:
Online Access:https://doi.org/10.4209/aaqr.2019.06.0279
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author Anshu Sharma
U. C. Kulshrestha
author_facet Anshu Sharma
U. C. Kulshrestha
author_sort Anshu Sharma
collection DOAJ
description Abstract The present study was carried out to understand the snow chemistry with special emphasis on the estimation of wet deposition fluxes and transportation of ionic species to the Himalayan regions from December 2015 to March 2017. All the snow samples were collected from three different sites of two locations, Jammu & Kashmir and Himachal Pradesh. In Jammu and Kashmir we have selected two sites, (an urban area Leh and other one was semi-urban area Beerwah). In Himachal Pradesh, we selected a site at Nirmand village which was a rural area. At Leh and Nirmand village, samples were showing higher alkalinity than at Beerwah site. The pH values of snow at Leh and Nirmand were recorded above 5.6 except one sample of both the sites. However, at Beerwah site almost 60% of the samples were found acidic (below 5.6) in nature. All these three sites showed three different means of neutralization and pH control. The study revealed that the high pH value of snowfall at Leh site could be due to the presence very high value of Ca2+ whereas the moderate pH at Nirmand village may be due to moderate concentration of Ca2+ and high NH4+. In contrast at Beerwah site, low pH is probably due to very low concentrations of all the major cations. This study also suggested that non-sea salt sources contributed a significant fraction of SO42−, K+, Ca2+, and Mg2+. However, on average, a significant amount of HCO3− was measured at all the three sites, indicating a substantial role of crustal sources in the study sites. Results of this study showed that these ionic species are contributed by local as well as long-distance sources in the region. Backward airmass trajectory analysis revealed that the ionic species were contributed by the airmasses coming from North Atlantic Ocean, Africa, Europe, Middle East, and Mediterranean region to all these sites through long-range transport (LRT).
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spelling doaj-art-bc843cb103c84b53997eeb823db433f42025-02-09T12:18:51ZengSpringerAerosol and Air Quality Research1680-85842071-14092020-04-012061249126510.4209/aaqr.2019.06.0279Wet Deposition and Long-range Transport of Major Ions Related to Snow at Northwestern Himalayas (India)Anshu Sharma0U. C. Kulshrestha1School of Environmental Sciences, Jawaharlal Nehru UniversitySchool of Environmental Sciences, Jawaharlal Nehru UniversityAbstract The present study was carried out to understand the snow chemistry with special emphasis on the estimation of wet deposition fluxes and transportation of ionic species to the Himalayan regions from December 2015 to March 2017. All the snow samples were collected from three different sites of two locations, Jammu & Kashmir and Himachal Pradesh. In Jammu and Kashmir we have selected two sites, (an urban area Leh and other one was semi-urban area Beerwah). In Himachal Pradesh, we selected a site at Nirmand village which was a rural area. At Leh and Nirmand village, samples were showing higher alkalinity than at Beerwah site. The pH values of snow at Leh and Nirmand were recorded above 5.6 except one sample of both the sites. However, at Beerwah site almost 60% of the samples were found acidic (below 5.6) in nature. All these three sites showed three different means of neutralization and pH control. The study revealed that the high pH value of snowfall at Leh site could be due to the presence very high value of Ca2+ whereas the moderate pH at Nirmand village may be due to moderate concentration of Ca2+ and high NH4+. In contrast at Beerwah site, low pH is probably due to very low concentrations of all the major cations. This study also suggested that non-sea salt sources contributed a significant fraction of SO42−, K+, Ca2+, and Mg2+. However, on average, a significant amount of HCO3− was measured at all the three sites, indicating a substantial role of crustal sources in the study sites. Results of this study showed that these ionic species are contributed by local as well as long-distance sources in the region. Backward airmass trajectory analysis revealed that the ionic species were contributed by the airmasses coming from North Atlantic Ocean, Africa, Europe, Middle East, and Mediterranean region to all these sites through long-range transport (LRT).https://doi.org/10.4209/aaqr.2019.06.0279SnowpHIonic chemistryWet deposition fluxBack trajectory analysis
spellingShingle Anshu Sharma
U. C. Kulshrestha
Wet Deposition and Long-range Transport of Major Ions Related to Snow at Northwestern Himalayas (India)
Aerosol and Air Quality Research
Snow
pH
Ionic chemistry
Wet deposition flux
Back trajectory analysis
title Wet Deposition and Long-range Transport of Major Ions Related to Snow at Northwestern Himalayas (India)
title_full Wet Deposition and Long-range Transport of Major Ions Related to Snow at Northwestern Himalayas (India)
title_fullStr Wet Deposition and Long-range Transport of Major Ions Related to Snow at Northwestern Himalayas (India)
title_full_unstemmed Wet Deposition and Long-range Transport of Major Ions Related to Snow at Northwestern Himalayas (India)
title_short Wet Deposition and Long-range Transport of Major Ions Related to Snow at Northwestern Himalayas (India)
title_sort wet deposition and long range transport of major ions related to snow at northwestern himalayas india
topic Snow
pH
Ionic chemistry
Wet deposition flux
Back trajectory analysis
url https://doi.org/10.4209/aaqr.2019.06.0279
work_keys_str_mv AT anshusharma wetdepositionandlongrangetransportofmajorionsrelatedtosnowatnorthwesternhimalayasindia
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