Novel Azo dyes containing a hydrazide-hydrazone moiety for dyeing polyester fabric

Abstract Novel azo dyes containing a hydrazide-hydrazone moiety linked to the benzothiazole nucleus are synthesized effectively in this study. The primary purpose of the study was to identify the best dyeing parameters, such as shade, temperature, pH, and time, in order to better understand the beha...

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Main Authors: Ali A. Ali, Mostafa A. Ismail, Walid E. Elgammal, Amany Belal, Ahmed J. Obaidullah, Ali Kh. Khalil, Gameel A. M. Elhagali, Mohamed S. A. El-Gaby
Format: Article
Language:English
Published: Nature Portfolio 2025-02-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-024-83565-3
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author Ali A. Ali
Mostafa A. Ismail
Walid E. Elgammal
Amany Belal
Ahmed J. Obaidullah
Ali Kh. Khalil
Gameel A. M. Elhagali
Mohamed S. A. El-Gaby
author_facet Ali A. Ali
Mostafa A. Ismail
Walid E. Elgammal
Amany Belal
Ahmed J. Obaidullah
Ali Kh. Khalil
Gameel A. M. Elhagali
Mohamed S. A. El-Gaby
author_sort Ali A. Ali
collection DOAJ
description Abstract Novel azo dyes containing a hydrazide-hydrazone moiety linked to the benzothiazole nucleus are synthesized effectively in this study. The primary purpose of the study was to identify the best dyeing parameters, such as shade, temperature, pH, and time, in order to better understand the behaviour of dispersed dyes during polyester dyeing. To achieve excellent colour strength in value (K/S = 26), the ideal dyeing conditions for disperse dye 4 were 30 min, pH of 8, and 110 °C at shade 3%. While the ideal dyeing conditions for disperse dyes dye 10 and dye 11 were 30 min, pH of 2, and 130 °C at a shade of 3%. Depending on the coupler moieties, the coloured polyester samples ranged in hue from beige to dark brown. Furthermore, the impact of substituent’s was examined in relation to colour strength (K/S) measures and colourimetric coordinates (CIEL*a*b*) of dyed polyester fabrics. The synthesized dispersed dyes are good options for giving polyester textiles a variety of stable hues and very good colour strength as well as exceptional fastness to light, washing, and crocking.
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spelling doaj-art-c16d4edd58a74cc4aaf0d9eb418ca9782025-02-09T12:29:19ZengNature PortfolioScientific Reports2045-23222025-02-0115112010.1038/s41598-024-83565-3Novel Azo dyes containing a hydrazide-hydrazone moiety for dyeing polyester fabricAli A. Ali0Mostafa A. Ismail1Walid E. Elgammal2Amany Belal3Ahmed J. Obaidullah4Ali Kh. Khalil5Gameel A. M. Elhagali6Mohamed S. A. El-Gaby7Department of Chemistry, Faculty of Science (Boys), Al-Azhar UniversityDepartment of Chemistry, College of Science, King Khalid UniversityDepartment of Chemistry, Faculty of Science (Boys), Al-Azhar UniversityDepartment of Pharmaceutical Chemistry, College of Pharmacy, Taif UniversityDepartment of Pharmaceutical Chemistry, College of Pharmacy, King Saud UniversityDepartment of Chemistry, Faculty of Science, Ain Shams UniversityDepartment of Chemistry, Faculty of Science (Boys), Al-Azhar UniversityDepartment of Chemistry, Faculty of Science (Boys), Al-Azhar UniversityAbstract Novel azo dyes containing a hydrazide-hydrazone moiety linked to the benzothiazole nucleus are synthesized effectively in this study. The primary purpose of the study was to identify the best dyeing parameters, such as shade, temperature, pH, and time, in order to better understand the behaviour of dispersed dyes during polyester dyeing. To achieve excellent colour strength in value (K/S = 26), the ideal dyeing conditions for disperse dye 4 were 30 min, pH of 8, and 110 °C at shade 3%. While the ideal dyeing conditions for disperse dyes dye 10 and dye 11 were 30 min, pH of 2, and 130 °C at a shade of 3%. Depending on the coupler moieties, the coloured polyester samples ranged in hue from beige to dark brown. Furthermore, the impact of substituent’s was examined in relation to colour strength (K/S) measures and colourimetric coordinates (CIEL*a*b*) of dyed polyester fabrics. The synthesized dispersed dyes are good options for giving polyester textiles a variety of stable hues and very good colour strength as well as exceptional fastness to light, washing, and crocking.https://doi.org/10.1038/s41598-024-83565-3PolyesterSynthesisDyesHydrazoneBenzophenone
spellingShingle Ali A. Ali
Mostafa A. Ismail
Walid E. Elgammal
Amany Belal
Ahmed J. Obaidullah
Ali Kh. Khalil
Gameel A. M. Elhagali
Mohamed S. A. El-Gaby
Novel Azo dyes containing a hydrazide-hydrazone moiety for dyeing polyester fabric
Scientific Reports
Polyester
Synthesis
Dyes
Hydrazone
Benzophenone
title Novel Azo dyes containing a hydrazide-hydrazone moiety for dyeing polyester fabric
title_full Novel Azo dyes containing a hydrazide-hydrazone moiety for dyeing polyester fabric
title_fullStr Novel Azo dyes containing a hydrazide-hydrazone moiety for dyeing polyester fabric
title_full_unstemmed Novel Azo dyes containing a hydrazide-hydrazone moiety for dyeing polyester fabric
title_short Novel Azo dyes containing a hydrazide-hydrazone moiety for dyeing polyester fabric
title_sort novel azo dyes containing a hydrazide hydrazone moiety for dyeing polyester fabric
topic Polyester
Synthesis
Dyes
Hydrazone
Benzophenone
url https://doi.org/10.1038/s41598-024-83565-3
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