Inhibition Mechanism of Shell Gasifier Coal Fly Ash Additive on Inner/Outer Layer Ash Deposition in Biomass Fluidized Bed Gasification

[Purposes] The research on the inhibition mechanism of ash deposition on the furnace wall of biomass fluidized bed gasification can provide fundamental data for the design of gasifiers with higher thermal efficiency and stable operation. [Methods] In this study, a self-designed deposition probe is u...

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Main Authors: XUE Haotian, QIN Yuhong, WANG Yuefeng, DU Yujia, WEI Yuexing, HE Chong, GUO Shugang, CAI Xingrui
Format: Article
Language:English
Published: Editorial Office of Journal of Taiyuan University of Technology 2025-01-01
Series:Taiyuan Ligong Daxue xuebao
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Online Access:https://tyutjournal.tyut.edu.cn/englishpaper/show-2360.html
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author XUE Haotian
QIN Yuhong
WANG Yuefeng
DU Yujia
WEI Yuexing
HE Chong
GUO Shugang
CAI Xingrui
author_facet XUE Haotian
QIN Yuhong
WANG Yuefeng
DU Yujia
WEI Yuexing
HE Chong
GUO Shugang
CAI Xingrui
author_sort XUE Haotian
collection DOAJ
description [Purposes] The research on the inhibition mechanism of ash deposition on the furnace wall of biomass fluidized bed gasification can provide fundamental data for the design of gasifiers with higher thermal efficiency and stable operation. [Methods] In this study, a self-designed deposition probe is used to collect the inner/outer layer of ash depositions on the furnace wall of corn straw and sargassum horneri, and Shell gasifier coal fly ash (Shell ash) is used as an additive. Analytical methods of IC, ICP-MS, SEM, and XRD are employed to quantitatively analyze the inhibition properties of ash deposition. [Findings] The results indicate that the condensation of alkali metal/alkaline earth metal sulphates and alkali metal chlorides play an important role in the formations of ash in the inner layers of corn straw and sargassum horneri gasification. When Shell ash is added at <15% and <10% to the two materials (mass ratio), the formation of phases such as leucite and orthoclase, which have higher relative melting temperatures, inhibits the adhesion of the ash particles and contributs to the loosening of the outer layer deposition ash structure. The inhibition mechanism suggests that both the base-to-acid ratio (RB/A) and n(SiO2+Al2O3) of the outer layer can effectively reflect the effect of Shell ash on the tendency of the outer layer deposition ash.
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publishDate 2025-01-01
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record_format Article
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spelling doaj-art-da528070f93b426e95ae8fa56a4f032f2025-02-12T03:34:22ZengEditorial Office of Journal of Taiyuan University of TechnologyTaiyuan Ligong Daxue xuebao1007-94322025-01-01561132410.16355/j.tyut.1007-9432.202402621007-9432(2025)01-0013-12Inhibition Mechanism of Shell Gasifier Coal Fly Ash Additive on Inner/Outer Layer Ash Deposition in Biomass Fluidized Bed GasificationXUE Haotian0QIN Yuhong1WANG Yuefeng2DU Yujia3WEI Yuexing4HE Chong5GUO Shugang6CAI Xingrui7College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi, ChinaCollege of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi, ChinaCollege of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi, ChinaCollege of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi, ChinaCollege of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi, ChinaCollege of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi, ChinaShanxi Provincial Center for Disease Control and Prevention, Taiyuan, Shanxi, ChinaCollege of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi, China[Purposes] The research on the inhibition mechanism of ash deposition on the furnace wall of biomass fluidized bed gasification can provide fundamental data for the design of gasifiers with higher thermal efficiency and stable operation. [Methods] In this study, a self-designed deposition probe is used to collect the inner/outer layer of ash depositions on the furnace wall of corn straw and sargassum horneri, and Shell gasifier coal fly ash (Shell ash) is used as an additive. Analytical methods of IC, ICP-MS, SEM, and XRD are employed to quantitatively analyze the inhibition properties of ash deposition. [Findings] The results indicate that the condensation of alkali metal/alkaline earth metal sulphates and alkali metal chlorides play an important role in the formations of ash in the inner layers of corn straw and sargassum horneri gasification. When Shell ash is added at <15% and <10% to the two materials (mass ratio), the formation of phases such as leucite and orthoclase, which have higher relative melting temperatures, inhibits the adhesion of the ash particles and contributs to the loosening of the outer layer deposition ash structure. The inhibition mechanism suggests that both the base-to-acid ratio (RB/A) and n(SiO2+Al2O3) of the outer layer can effectively reflect the effect of Shell ash on the tendency of the outer layer deposition ash.https://tyutjournal.tyut.edu.cn/englishpaper/show-2360.htmlbiomassgasificationash depositioninhibitioninner layer ash depositionouter layer ash depositioncl
spellingShingle XUE Haotian
QIN Yuhong
WANG Yuefeng
DU Yujia
WEI Yuexing
HE Chong
GUO Shugang
CAI Xingrui
Inhibition Mechanism of Shell Gasifier Coal Fly Ash Additive on Inner/Outer Layer Ash Deposition in Biomass Fluidized Bed Gasification
Taiyuan Ligong Daxue xuebao
biomass
gasification
ash deposition
inhibition
inner layer ash deposition
outer layer ash deposition
cl
title Inhibition Mechanism of Shell Gasifier Coal Fly Ash Additive on Inner/Outer Layer Ash Deposition in Biomass Fluidized Bed Gasification
title_full Inhibition Mechanism of Shell Gasifier Coal Fly Ash Additive on Inner/Outer Layer Ash Deposition in Biomass Fluidized Bed Gasification
title_fullStr Inhibition Mechanism of Shell Gasifier Coal Fly Ash Additive on Inner/Outer Layer Ash Deposition in Biomass Fluidized Bed Gasification
title_full_unstemmed Inhibition Mechanism of Shell Gasifier Coal Fly Ash Additive on Inner/Outer Layer Ash Deposition in Biomass Fluidized Bed Gasification
title_short Inhibition Mechanism of Shell Gasifier Coal Fly Ash Additive on Inner/Outer Layer Ash Deposition in Biomass Fluidized Bed Gasification
title_sort inhibition mechanism of shell gasifier coal fly ash additive on inner outer layer ash deposition in biomass fluidized bed gasification
topic biomass
gasification
ash deposition
inhibition
inner layer ash deposition
outer layer ash deposition
cl
url https://tyutjournal.tyut.edu.cn/englishpaper/show-2360.html
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