Mechanism of methanol and formaldehyde emissions from methanol-fueled engines

Methanol, as a low-carbon fuel, has broad application prospects in engines. The mechanism of methanol and formaldehyde was investigated respectively in a methanol premixed combustion test bench (PCTB) and a 304 stainless-steel flow reactor (SFR). The results of PCTB indicate that methanol cannot esc...

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Main Authors: Fangjie Liu, Hengrui Guo, Xinguo Zheng, Haizhao Li, Xin Wang
Format: Article
Language:English
Published: Elsevier 2025-04-01
Series:Fuel Processing Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0378382025000013
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author Fangjie Liu
Hengrui Guo
Xinguo Zheng
Haizhao Li
Xin Wang
author_facet Fangjie Liu
Hengrui Guo
Xinguo Zheng
Haizhao Li
Xin Wang
author_sort Fangjie Liu
collection DOAJ
description Methanol, as a low-carbon fuel, has broad application prospects in engines. The mechanism of methanol and formaldehyde was investigated respectively in a methanol premixed combustion test bench (PCTB) and a 304 stainless-steel flow reactor (SFR). The results of PCTB indicate that methanol cannot escape from the flame surface to form unburned methanol emissions. Methanol was partially oxidized to formaldehyde in the exhaust system when methanol gas is fed into the upstream exhaust. The results of SFR indicate that the onset temperature of methanol oxidation is approximately 628 K. The methanol concentration decreases rapidly with increasing temperature from 628 to 950 K. Formaldehyde increases firstly and then decreases with increasing temperature. The concentration of formaldehyde reaches the maximum at the critical temperature. At flow velocities of 8, 12, 16, 20 and 24 m/s, the critical temperature is 812, 823.4, 830, 845.5 and 850 K, respectively. This work investigates the mechanism of methanol and formaldehyde at different temperatures, flow velocities, and oxygen concentrations, and provides valuable insights into the control of methanol and formaldehyde emissions from methanol engines.
format Article
id doaj-art-e34a3f59a27d499b8c831078221fb6fb
institution Kabale University
issn 0378-3820
language English
publishDate 2025-04-01
publisher Elsevier
record_format Article
series Fuel Processing Technology
spelling doaj-art-e34a3f59a27d499b8c831078221fb6fb2025-02-09T04:59:41ZengElsevierFuel Processing Technology0378-38202025-04-01268108177Mechanism of methanol and formaldehyde emissions from methanol-fueled enginesFangjie Liu0Hengrui Guo1Xinguo Zheng2Haizhao Li3Xin Wang4Corresponding author.; College of Vehicle and Traffic Engineering, Henan University of Science and Technology, Luoyang 471003, ChinaCollege of Vehicle and Traffic Engineering, Henan University of Science and Technology, Luoyang 471003, ChinaCollege of Vehicle and Traffic Engineering, Henan University of Science and Technology, Luoyang 471003, ChinaCollege of Vehicle and Traffic Engineering, Henan University of Science and Technology, Luoyang 471003, ChinaCollege of Vehicle and Traffic Engineering, Henan University of Science and Technology, Luoyang 471003, ChinaMethanol, as a low-carbon fuel, has broad application prospects in engines. The mechanism of methanol and formaldehyde was investigated respectively in a methanol premixed combustion test bench (PCTB) and a 304 stainless-steel flow reactor (SFR). The results of PCTB indicate that methanol cannot escape from the flame surface to form unburned methanol emissions. Methanol was partially oxidized to formaldehyde in the exhaust system when methanol gas is fed into the upstream exhaust. The results of SFR indicate that the onset temperature of methanol oxidation is approximately 628 K. The methanol concentration decreases rapidly with increasing temperature from 628 to 950 K. Formaldehyde increases firstly and then decreases with increasing temperature. The concentration of formaldehyde reaches the maximum at the critical temperature. At flow velocities of 8, 12, 16, 20 and 24 m/s, the critical temperature is 812, 823.4, 830, 845.5 and 850 K, respectively. This work investigates the mechanism of methanol and formaldehyde at different temperatures, flow velocities, and oxygen concentrations, and provides valuable insights into the control of methanol and formaldehyde emissions from methanol engines.http://www.sciencedirect.com/science/article/pii/S0378382025000013Methanol-fueled engineEngine exhaust systemExhaust temperatureUnburned methanol oxidationFormaldehyde emission
spellingShingle Fangjie Liu
Hengrui Guo
Xinguo Zheng
Haizhao Li
Xin Wang
Mechanism of methanol and formaldehyde emissions from methanol-fueled engines
Fuel Processing Technology
Methanol-fueled engine
Engine exhaust system
Exhaust temperature
Unburned methanol oxidation
Formaldehyde emission
title Mechanism of methanol and formaldehyde emissions from methanol-fueled engines
title_full Mechanism of methanol and formaldehyde emissions from methanol-fueled engines
title_fullStr Mechanism of methanol and formaldehyde emissions from methanol-fueled engines
title_full_unstemmed Mechanism of methanol and formaldehyde emissions from methanol-fueled engines
title_short Mechanism of methanol and formaldehyde emissions from methanol-fueled engines
title_sort mechanism of methanol and formaldehyde emissions from methanol fueled engines
topic Methanol-fueled engine
Engine exhaust system
Exhaust temperature
Unburned methanol oxidation
Formaldehyde emission
url http://www.sciencedirect.com/science/article/pii/S0378382025000013
work_keys_str_mv AT fangjieliu mechanismofmethanolandformaldehydeemissionsfrommethanolfueledengines
AT hengruiguo mechanismofmethanolandformaldehydeemissionsfrommethanolfueledengines
AT xinguozheng mechanismofmethanolandformaldehydeemissionsfrommethanolfueledengines
AT haizhaoli mechanismofmethanolandformaldehydeemissionsfrommethanolfueledengines
AT xinwang mechanismofmethanolandformaldehydeemissionsfrommethanolfueledengines