A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution

Metal ions with smaller radii than Pb2+ can stabilize CsPbBr3 NCs' cubic structure by lattice shrinkage, but lacking sensing research. Herein, Ni-substituting CsPbBr3 NCs were prepared to rapidly and accurately detect water content (WC) in edible oils. CsPb0.95Ni0.05Br3 NCs had the highest fluo...

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Main Authors: Qin Ye, Penghao Zhu, Xianghe Meng, Jie Li, Yuanchao Lu
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Food Chemistry: X
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590157525000422
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author Qin Ye
Penghao Zhu
Xianghe Meng
Jie Li
Yuanchao Lu
author_facet Qin Ye
Penghao Zhu
Xianghe Meng
Jie Li
Yuanchao Lu
author_sort Qin Ye
collection DOAJ
description Metal ions with smaller radii than Pb2+ can stabilize CsPbBr3 NCs' cubic structure by lattice shrinkage, but lacking sensing research. Herein, Ni-substituting CsPbBr3 NCs were prepared to rapidly and accurately detect water content (WC) in edible oils. CsPb0.95Ni0.05Br3 NCs had the highest fluorescence intensity, approximately 125 % of CsPbBr3 NCs. The results displayed that CsPb0.95Ni0.05Br3 NCs were uniformly quadrilateral crystalline packing (8.78 ± 0.28 nm particle size) with inter-planar distances of 0.41, 0.33, and 0.29 nm. Given the fluorescence quenching behavior, a superior linear curve between fluorescence-decreased ratio and WC was established within 0–3 ‰ (v/v) and a detection limitation of 0.042 ‰. Furthermore, excellent precision and accuracy were verified in various oils with a relative error of 2.06 %. It was suggested that water destroyed and dissolved CsPb0.95Ni0.05Br3 NCs' crystal structure to induce fluorescence quenching. Thus, Pb-site substitutions of CsPbBr3 NCs enhanced the sensing performance, enlightening other elements-substituted CsPbBr3 NCs for sensing.
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institution Kabale University
issn 2590-1575
language English
publishDate 2025-01-01
publisher Elsevier
record_format Article
series Food Chemistry: X
spelling doaj-art-5978afeec5b64044b88c162818e908002025-02-12T05:32:30ZengElsevierFood Chemistry: X2590-15752025-01-0125102196A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolutionQin Ye0Penghao Zhu1Xianghe Meng2Jie Li3Yuanchao Lu4Institute of Food Sciences, Zhejiang, Academy of Agricultural Sciences, Hangzhou 310014, ChinaCollege of Food Science and Technology, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Food Science and Technology, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China; Corresponding authors.College of Food Science and Technology, Zhejiang University of Technology, Hangzhou 310014, China; Corresponding authors.Metal ions with smaller radii than Pb2+ can stabilize CsPbBr3 NCs' cubic structure by lattice shrinkage, but lacking sensing research. Herein, Ni-substituting CsPbBr3 NCs were prepared to rapidly and accurately detect water content (WC) in edible oils. CsPb0.95Ni0.05Br3 NCs had the highest fluorescence intensity, approximately 125 % of CsPbBr3 NCs. The results displayed that CsPb0.95Ni0.05Br3 NCs were uniformly quadrilateral crystalline packing (8.78 ± 0.28 nm particle size) with inter-planar distances of 0.41, 0.33, and 0.29 nm. Given the fluorescence quenching behavior, a superior linear curve between fluorescence-decreased ratio and WC was established within 0–3 ‰ (v/v) and a detection limitation of 0.042 ‰. Furthermore, excellent precision and accuracy were verified in various oils with a relative error of 2.06 %. It was suggested that water destroyed and dissolved CsPb0.95Ni0.05Br3 NCs' crystal structure to induce fluorescence quenching. Thus, Pb-site substitutions of CsPbBr3 NCs enhanced the sensing performance, enlightening other elements-substituted CsPbBr3 NCs for sensing.http://www.sciencedirect.com/science/article/pii/S2590157525000422CsPb0,95Ni0,05Br3 NCsWater contentEdible oilsFluorescence sensorsStructure destruction and dissolution
spellingShingle Qin Ye
Penghao Zhu
Xianghe Meng
Jie Li
Yuanchao Lu
A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution
Food Chemistry: X
CsPb0,95Ni0,05Br3 NCs
Water content
Edible oils
Fluorescence sensors
Structure destruction and dissolution
title A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution
title_full A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution
title_fullStr A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution
title_full_unstemmed A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution
title_short A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution
title_sort cspb0 95ni0 05br3 ncs based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution
topic CsPb0,95Ni0,05Br3 NCs
Water content
Edible oils
Fluorescence sensors
Structure destruction and dissolution
url http://www.sciencedirect.com/science/article/pii/S2590157525000422
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