A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution
Metal ions with smaller radii than Pb2+ can stabilize CsPbBr3 NCs' cubic structure by lattice shrinkage, but lacking sensing research. Herein, Ni-substituting CsPbBr3 NCs were prepared to rapidly and accurately detect water content (WC) in edible oils. CsPb0.95Ni0.05Br3 NCs had the highest fluo...
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Elsevier
2025-01-01
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2590157525000422 |
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author | Qin Ye Penghao Zhu Xianghe Meng Jie Li Yuanchao Lu |
author_facet | Qin Ye Penghao Zhu Xianghe Meng Jie Li Yuanchao Lu |
author_sort | Qin Ye |
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description | Metal ions with smaller radii than Pb2+ can stabilize CsPbBr3 NCs' cubic structure by lattice shrinkage, but lacking sensing research. Herein, Ni-substituting CsPbBr3 NCs were prepared to rapidly and accurately detect water content (WC) in edible oils. CsPb0.95Ni0.05Br3 NCs had the highest fluorescence intensity, approximately 125 % of CsPbBr3 NCs. The results displayed that CsPb0.95Ni0.05Br3 NCs were uniformly quadrilateral crystalline packing (8.78 ± 0.28 nm particle size) with inter-planar distances of 0.41, 0.33, and 0.29 nm. Given the fluorescence quenching behavior, a superior linear curve between fluorescence-decreased ratio and WC was established within 0–3 ‰ (v/v) and a detection limitation of 0.042 ‰. Furthermore, excellent precision and accuracy were verified in various oils with a relative error of 2.06 %. It was suggested that water destroyed and dissolved CsPb0.95Ni0.05Br3 NCs' crystal structure to induce fluorescence quenching. Thus, Pb-site substitutions of CsPbBr3 NCs enhanced the sensing performance, enlightening other elements-substituted CsPbBr3 NCs for sensing. |
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institution | Kabale University |
issn | 2590-1575 |
language | English |
publishDate | 2025-01-01 |
publisher | Elsevier |
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series | Food Chemistry: X |
spelling | doaj-art-5978afeec5b64044b88c162818e908002025-02-12T05:32:30ZengElsevierFood Chemistry: X2590-15752025-01-0125102196A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolutionQin Ye0Penghao Zhu1Xianghe Meng2Jie Li3Yuanchao Lu4Institute of Food Sciences, Zhejiang, Academy of Agricultural Sciences, Hangzhou 310014, ChinaCollege of Food Science and Technology, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Food Science and Technology, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China; Corresponding authors.College of Food Science and Technology, Zhejiang University of Technology, Hangzhou 310014, China; Corresponding authors.Metal ions with smaller radii than Pb2+ can stabilize CsPbBr3 NCs' cubic structure by lattice shrinkage, but lacking sensing research. Herein, Ni-substituting CsPbBr3 NCs were prepared to rapidly and accurately detect water content (WC) in edible oils. CsPb0.95Ni0.05Br3 NCs had the highest fluorescence intensity, approximately 125 % of CsPbBr3 NCs. The results displayed that CsPb0.95Ni0.05Br3 NCs were uniformly quadrilateral crystalline packing (8.78 ± 0.28 nm particle size) with inter-planar distances of 0.41, 0.33, and 0.29 nm. Given the fluorescence quenching behavior, a superior linear curve between fluorescence-decreased ratio and WC was established within 0–3 ‰ (v/v) and a detection limitation of 0.042 ‰. Furthermore, excellent precision and accuracy were verified in various oils with a relative error of 2.06 %. It was suggested that water destroyed and dissolved CsPb0.95Ni0.05Br3 NCs' crystal structure to induce fluorescence quenching. Thus, Pb-site substitutions of CsPbBr3 NCs enhanced the sensing performance, enlightening other elements-substituted CsPbBr3 NCs for sensing.http://www.sciencedirect.com/science/article/pii/S2590157525000422CsPb0,95Ni0,05Br3 NCsWater contentEdible oilsFluorescence sensorsStructure destruction and dissolution |
spellingShingle | Qin Ye Penghao Zhu Xianghe Meng Jie Li Yuanchao Lu A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution Food Chemistry: X CsPb0,95Ni0,05Br3 NCs Water content Edible oils Fluorescence sensors Structure destruction and dissolution |
title | A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution |
title_full | A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution |
title_fullStr | A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution |
title_full_unstemmed | A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution |
title_short | A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution |
title_sort | cspb0 95ni0 05br3 ncs based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution |
topic | CsPb0,95Ni0,05Br3 NCs Water content Edible oils Fluorescence sensors Structure destruction and dissolution |
url | http://www.sciencedirect.com/science/article/pii/S2590157525000422 |
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